Skip to main content
Ch 18: A Macroscopic Description of Matter

Chapter 18, Problem 20

A 1.0 m ✕ 1.0 m ✕ 1.0 m cube of nitrogen gas is at 20℃ and 1.0 atm. Estimate the number of molecules in the cube with a speed between 700 m/s and 1000 m/s.

Verified Solution
Video duration:
5m
This video solution was recommended by our tutors as helpful for the problem above.
295
views
Was this helpful?

Video transcript

Hey, everyone. Let's go through this practice problem. A spherical container with a diameter of 50 centimeters is filled with helium gas at a temperature of 25 degrees Celsius and a pressure of two atmospheres estimate the number of helium gas molecules in the container that have a speed between 500 m per 2nd and m per second. Assume that the container is perfectly insulated and that the helium gas behaves like an ideal gas. Consider 2.2% of helium gas molecules have a speed between 500 m per 2nd and 1000 m per second. Option A 3.22 multiplied by 10 to the power of 24. Option B 6.15 multiplied by 10 to the power of 24. Option C 7.9 multiplied by 10 to the power of 22. And option D 5.31 multiplied by 10 to the power of 22. This problem isn't too complicated. We can use the variables we've been given along with the ideal gas law to figure out the total number of molecules for the gas. Then once we figure the total number, we can use the percentage we were given or the amount that are within the range that we're looking for to shorten the total number to the number that just fits in with the 2.2%. First, we can find the volume of the gas by using the fact that we're told the gas is in a spherical container. Recalled that the volume of a sphere is equal to four divided by three, multiplied by pi multiplied by the cube of the radius. We're told that the spherical chamber has a diameter of 50 centimeters. So the radius is going to be half of that or 25 centimeters converting this into meters. So 0.25 m and if we put this into a calculator, then we find a volume for the chamber of about 0. 545 cubic meters. So this is the volume of the gas. We also want to consider the pressure. We're told that there is a pressure of two atmospheres. But in order for this pressure to work with the ideal gas law, this seems to be converted into pascals. So we we convert to pascals and multiplying by 1.13, multiplied by 10 of the power power of five pascals per one atmosphere. We put that into a calculator. We find a pressure of about 202,600 pascals. Finally, the temperature we've been given of the gas is 25 degrees Celsius. In order to make the temperature work with the ideal gas law, this needs to be converted into Kelvins and we can convert to Kelvins by adding 273 we put this into a calculator. Then we find a new temperature of about 298. Kelvins recall that the form of the ideal gas law that includes the number of particles is the form that states that the pressure of the gas multiplied by the volume of the gas is equal to the number of particles multiplied by the Boltzmann constant multiplied by the temperature we're trying to solve for the number of particles M. So let's divide both sides of the equation by K T. And we find that the number is equal to the pressure multiplied by the volume divided by K T. Now let's plug into this the variables that we found earlier. So for P that's 202,600 pascals or V, that's 0.6545 cubic meters K is the Boltzmann constant. So that's 1.38 multiplied by 10 to the power of a negative Jews per Kelvin. And the temperature is 298 Kelvins as we discussed earlier. If we put this into a calculator, then we find a number of particles of about 3. multiplied by 10 to the power of 24. So this is the total number of molecules in the gas. But the problem tells us that only 2.2% of the molecules will be within the speed range we're looking for. So let's take this number of molecules we found and multiply it by the percentage 2.22. So point 022, multiplied by 3.22, multiplied by 10 to the power of 24. If we put this into a calculator, then we find a new number of particles of about 7. multiplied by 10 to the power of 22. And so this is our answer to the problem since we've considered the percentage now and everything. If we look at our multiple choice options, we can see if this agrees with option C. So option C is the correct answer to the problem and that's it for this problem. I hope this video helped you out. If you need more practice, please consider checking out some of our other videos which will give you more experience with these types of problems, but that's it for now. And I hope you all have a lovely day. Bye bye.
Related Practice
Textbook Question
A 6.0-cm-diameter cylinder of nitrogen gas has a 4.0-cm-thick movable copper piston. The cylinder is oriented vertically, as shown in FIGURE P19.49, and the air above the piston is evacuated. When the gas temperature is 20°C, the piston floats 20 cm above the bottom of the cylinder. a. What is the gas pressure?
204
views
1
rank
Textbook Question
A 6.0-cm-diameter cylinder of nitrogen gas has a 4.0-cm-thick movable copper piston. The cylinder is oriented vertically, as shown in FIGURE P19.49, and the air above the piston is evacuated. When the gas temperature is 20°C, the piston floats 20 cm above the bottom of the cylinder. c. What is the new equilibrium temperature of the gas?
238
views
Textbook Question
14 g of nitrogen gas at STP are pressurized in an isochoric process to a pressure of 20 atm. What are (a) the final temperature,
283
views
Textbook Question
Photons of light scatter off molecules, and the distance you can see through a gas is proportional to the mean free path of photons through the gas. Photons are not gas molecules, so the mean free path of a photon is not given by Equation 20.3, but its dependence on the number density of the gas and on the molecular radius is the same. Suppose you are in a smoggy city and can barely see buildings 500 m away. b. How far would you be able to see if the temperature suddenly rose from 20°C to a blazing hot 1500°C with the pressure unchanged?
242
views
Textbook Question
Interstellar space, far from any stars, is filled with a very low density of hydrogen atoms (H, not H₂). The number density is about 1 atom/cm³ and the temperature is about 3 K. a. Estimate the pressure in interstellar space. Give your answer in Pa and in atm.
284
views
Textbook Question
Equation 20.3 is the mean free path of a particle through a gas of identical particles of equal radius. An electron can be thought of as a point particle with zero radius. b. Electrons travel 3.0 km through the Stanford Linear Accelerator. In order for scattering losses to be negligible, the pressure inside the accelerator tube must be reduced to the point where the mean free path is at least 50 km. What is the maximum possible pressure inside the accelerator tube, assuming T = 20℃? Give your answer in both Pa and atm.
277
views