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Ch 18: A Macroscopic Description of Matter
Chapter 18, Problem 20

Photons of light scatter off molecules, and the distance you can see through a gas is proportional to the mean free path of photons through the gas. Photons are not gas molecules, so the mean free path of a photon is not given by Equation 20.3, but its dependence on the number density of the gas and on the molecular radius is the same. Suppose you are in a smoggy city and can barely see buildings 500 m away. b. How far would you be able to see if the temperature suddenly rose from 20°C to a blazing hot 1500°C with the pressure unchanged?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Mean Free Path

The mean free path is the average distance a particle travels between collisions with other particles. In the context of photons scattering off gas molecules, it describes how far a photon can travel before interacting with a molecule. This distance is influenced by the number density of the gas and the size of the molecules, which affects the likelihood of scattering events.
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Mean Free Path

Temperature and Gas Density

Temperature affects the kinetic energy of gas molecules, which in turn influences their density. As temperature increases, gas molecules move faster and can spread out, potentially reducing the number density of the gas. In the scenario of rising temperature from 20°C to 1500°C, the change in density will impact the mean free path of photons, altering visibility through the gas.
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Scattering of Photons

Scattering occurs when photons interact with particles in a medium, such as gas molecules. The extent of scattering determines how far light can travel through a medium before being absorbed or redirected. In a smoggy environment, increased scattering due to higher particle density reduces visibility, while changes in temperature can modify the scattering behavior and thus the distance light can travel.
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Related Practice
Textbook Question
A 6.0-cm-diameter cylinder of nitrogen gas has a 4.0-cm-thick movable copper piston. The cylinder is oriented vertically, as shown in FIGURE P19.49, and the air above the piston is evacuated. When the gas temperature is 20°C, the piston floats 20 cm above the bottom of the cylinder. c. What is the new equilibrium temperature of the gas?
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Textbook Question
14 g of nitrogen gas at STP are pressurized in an isochoric process to a pressure of 20 atm. What are (a) the final temperature,
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Textbook Question
A 1.0 m ✕ 1.0 m ✕ 1.0 m cube of nitrogen gas is at 20℃ and 1.0 atm. Estimate the number of molecules in the cube with a speed between 700 m/s and 1000 m/s.
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Textbook Question
Interstellar space, far from any stars, is filled with a very low density of hydrogen atoms (H, not H₂). The number density is about 1 atom/cm³ and the temperature is about 3 K. a. Estimate the pressure in interstellar space. Give your answer in Pa and in atm.
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Textbook Question
Equation 20.3 is the mean free path of a particle through a gas of identical particles of equal radius. An electron can be thought of as a point particle with zero radius. b. Electrons travel 3.0 km through the Stanford Linear Accelerator. In order for scattering losses to be negligible, the pressure inside the accelerator tube must be reduced to the point where the mean free path is at least 50 km. What is the maximum possible pressure inside the accelerator tube, assuming T = 20℃? Give your answer in both Pa and atm.
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