You are given a gray substance that melts at 700 °C; the solid is a conductor of electricity and is insoluble in water. Which type of solid (molecular, metallic, covalent-network, or ionic) might this substance be?
Ch.12 - Solids and Modern Materials
Chapter 12, Problem 21b
Two patterns of packing for two different circles of the same size are shown here. For each structure (b) determine the angle between the lattice vectors, g, and determine whether the lattice vectors are of the same length or of different lengths; (i)
(ii)
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Lattice Vectors
Lattice vectors are the fundamental building blocks of a crystal lattice, defining the periodic arrangement of points in space. They are represented as vectors that connect points in the lattice, and their lengths and angles determine the symmetry and structure of the crystal. In the context of the question, analyzing the lengths and angles of the lattice vectors helps identify the packing arrangement of the circles.
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Crystalline Structures
Crystalline structures are ordered arrangements of atoms, ions, or molecules in a solid, characterized by repeating patterns. The two packing patterns shown in the image represent different crystalline arrangements, which can affect properties such as density and stability. Understanding these structures is essential for determining the angles and lengths of the lattice vectors in the given question.
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Angle Between Lattice Vectors
The angle between lattice vectors is a critical parameter that influences the geometry of the crystal lattice. It can indicate the type of packing arrangement, such as square or hexagonal packing, and is essential for understanding the spatial relationships between the particles in the lattice. In the question, calculating this angle is necessary to differentiate between the two packing patterns presented.
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Related Practice
Textbook Question
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Textbook Question
(a) Draw a picture that represents a crystalline solid at the atomic level.
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Textbook Question
(b) Now draw a picture that represents an amorphous solid at the atomic level.
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Textbook Question
Two patterns of packing two different circles of the same size are shown here. For each structure (c) determine the type of two-dimensional lattice (from Figure 12.4). (i)
(ii)
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Textbook Question
Imagine the primitive cubic lattice. Now imagine grabbing the top of it and stretching it straight up. All angles remain 90. What kind of primitive lattice have you made?
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Textbook Question
Which of the three-dimensional primitive lattices has a unit cell where none of the internal angles is 90? (a) Orthorhombic, (b) hexagonal, (c) rhombohedral, (d) triclinic, (e) both rhombohedral and triclinic.
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