Problem 31
A hydrogen-filled balloon is ignited and 3 g of hydrogen is reacted with 24 g of oxygen. How many grams of water vapor form? (Assume that water vapor is the only product.)
Problem 32
An automobile gasoline tank holds 42 kg of gasoline. When the gasoline burns, 168 kg of oxygen is consumed, and carbon dioxide and water are produced. What is the total combined mass of carbon dioxide and water that is produced?
Problem 33
Two samples of carbon tetrachloride are decomposed into their constituent elements. One sample produces 38.9 g of carbon and 448 g of chlorine, and the other sample produces 14.8 g of carbon and 134 g of chlorine. Are these results consistent with the law of definite proportions? Explain your answer.
Problem 35
Upon decomposition, one sample of magnesium fluoride produces 1.65 kg of magnesium and 2.57 kg of fluorine. A second sample produces 2.72 kg of magnesium. How much fluorine (in grams) does the second sample produce?
Problem 36
The mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produces 45.1 g of sodium upon decomposition. How much fluorine (in grams) forms?
Problem 37
Two different compounds containing osmium and oxygen have the following masses of oxygen per gram of osmium: 0.168 and 0.3369 g. Show that these amounts are consistent with the law of multiple proportions.
Problem 38
Palladium forms three different compounds with sulfur. The mass of sulfur per gram of palladium in each compound is listed here. Show that these masses are consistent with the law of multiple proportions. Compound Grams S per Gram Pd A 0.603 B 0.301 C 0.151
Problem 39
Sulfur and oxygen form both sulfur dioxide and sulfur trioxide. When samples of these are decomposed, the sulfur dioxide produces 3.49 g oxygen and 3.50 g sulfur, while the sulfur trioxide produces 6.75 g oxygen and 4.50 g sulfur. Calculate the mass of oxygen per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.
Problem 40
Sulfur and fluorine form several different compounds including sulfur hexafluoride and sulfur tetrafluoride. Decomposition of a sample of sulfur hexafluoride produces 4.45 g of fluorine and 1.25 g of sulfur, while decomposition of a sample of sulfur tetrafluoride produces 4.43 g of fluorine and 1.87 g of sulfur. Calculate the mass of fluorine per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.
Problem 41
Which statements are consistent with Dalton's atomic theory as it was originally stated? Why? a. Sulfur and oxygen atoms have the same mass. b. All cobalt atoms are identical. c. Potassium and chlorine atoms combine in a 1:1 ratio to form potassium chloride. d. Lead atoms can be converted into gold.
Problem 42
Which statements are inconsistent with Dalton's atomic theory as it was originally stated? Why? a. All carbon atoms are identical. b. An oxygen atom combines with 1.5 hydrogen atoms to form a water molecule. c. Two oxygen atoms combine with a carbon atom to form a carbon dioxide molecule. d. The formation of a compound often involves the destruction of one or more atoms.
Problem 43
Which statements are consistent with Rutherford's nuclear theory as it was originally stated? Why? a. The volume of an atom is mostly empty space. b. The nucleus of an atom is small compared to the size of the atom. c. Neutral lithium atoms contain more neutrons than protons. d. Neutral lithium atoms contain more protons than electrons.
Problem 44
Which statements are inconsistent with Rutherford's nuclear theory as it was originally stated? Why? a. Since electrons are smaller than protons, and since a hydrogen atom contains only one proton and one electron, it must follow that the volume of a hydrogen atom is mostly due to the proton. b. A nitrogen atom has 7 protons in its nucleus and 7 electrons outside of its nucleus. c. A phosphorus atom has 15 protons in its nucleus and 150 electrons outside of its nucleus. d. The majority of the mass of a fluorine atom is due to its 9 electrons.
Problem 45
A chemist in an imaginary universe, where electrons have a different charge than they do in our universe, performs the Millikan oil drop experiment to measure the electron's charge. The charges of several drops are recorded here. What is the charge of the electron in this imaginary universe? Drop # Charge A -6.9 * 10 - 19 C B -9.2 * 10 - 19 C C -11.5 * 10 - 19 C D -4.6 * 10 - 19 C
Problem 46
Imagine a unit of charge called the zorg. A chemist performs the oil drop experiment and measures the charge of each drop in zorgs. Based on the results shown here, what is the charge of the electron in zorgs (z)? How many electrons are in each drop? Drop # Charge A -4.8 * 10 - 9 z B -9.6 * 10 - 9 z C -6.4 * 10 - 9 z D -12.8 * 10 - 9 z
Problem 47a
On a dry day, your body can accumulate static charge from walking across a carpet or from brushing your hair. If your body develops a charge of -22 µC (microcoulombs), how many excess electrons has it acquired?
Problem 47b
On a dry day, your body can accumulate static charge from walking across a carpet or from brushing your hair. If your body develops a charge of -22 mC (microcoulombs), what is their collective mass?
Problem 48
How many electrons are necessary to produce a charge of -11.0 C? What is the mass of this many electrons?
Problem 49
Which statements about subatomic particles are true? a. If an atom has an equal number of protons and electrons, it will be charge-neutral. b. Electrons are attracted to protons. c. Electrons are much lighter than neutrons. d. Protons have twice the mass of neutrons.
Problem 50
Which statements about subatomic particles are false? a. Protons and electrons have charges of the same magnitude but opposite sign. b. Protons have about the same mass as neutrons. c. Some atoms don't have any protons. d. Protons and neutrons have charges of the same magnitude but opposite signs.
Problem 51
How many electrons does it take to equal the mass of a proton?
Problem 52
A helium nucleus has two protons and two neutrons. How many electrons does it take to equal the mass of a helium nucleus?
Problem 53a
Write isotopic symbols in the form X-A (e.g., C-13) for each isotope. a. the hydrogen isotope with two neutrons
Problem 53b
Write isotopic symbols in the form X-A (e.g., C-13) for each isotope. b. the gold isotope with 119 neutrons
Problem 53c
Write isotopic symbols in the form X-A (e.g., C-13) for each isotope. c. the gold isotope with 122 neutrons
Problem 53d
Write isotopic symbols in the form X-A (e.g., C-13) for each isotope. d. the uranium isotope with 143 neutrons
Problem 55a
Write isotopic symbols in the form AZX for each isotope. a. the nickel isotope with 32 neutrons
Problem 55b
Write isotopic symbols in the form AZX for each isotope. b. the iron isotope with 30 neutrons
Problem 55c
Write isotopic symbols in the form AZX for each isotope. c. the rubidium isotope with 45 neutrons
Problem 57a
Determine the number of protons and the number of neutrons in each isotope. a. 14 7N
Ch.2 - Atoms & Elements
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