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Ch.2 - Atoms & Elements
Chapter 2, Problem 42

Which statements are inconsistent with Dalton's atomic theory as it was originally stated? Why? a. All carbon atoms are identical. b. An oxygen atom combines with 1.5 hydrogen atoms to form a water molecule. c. Two oxygen atoms combine with a carbon atom to form a carbon dioxide molecule. d. The formation of a compound often involves the destruction of one or more atoms.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Dalton's Atomic Theory

Dalton's atomic theory, proposed in the early 19th century, states that matter is composed of indivisible atoms, each element consists of identical atoms, and chemical reactions involve the rearrangement of these atoms. This theory laid the groundwork for modern chemistry by introducing the idea that atoms combine in fixed ratios to form compounds.
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Law of Conservation of Mass

The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction. This principle implies that the total mass of reactants must equal the total mass of products, which contradicts the idea of atoms being destroyed during the formation of compounds, as suggested in option d.
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Stoichiometry and Atomic Ratios

Stoichiometry involves the calculation of reactants and products in chemical reactions based on the conservation of mass and the fixed ratios of atoms. According to Dalton's theory, atoms combine in whole number ratios, making the statement about an oxygen atom combining with 1.5 hydrogen atoms inconsistent with the theory, as it suggests a fractional atom ratio.
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Related Practice
Textbook Question

Sulfur and oxygen form both sulfur dioxide and sulfur trioxide. When samples of these are decomposed, the sulfur dioxide produces 3.49 g oxygen and 3.50 g sulfur, while the sulfur trioxide produces 6.75 g oxygen and 4.50 g sulfur. Calculate the mass of oxygen per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.

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Textbook Question

Sulfur and fluorine form several different compounds including sulfur hexafluoride and sulfur tetrafluoride. Decomposition of a sample of sulfur hexafluoride produces 4.45 g of fluorine and 1.25 g of sulfur, while decomposition of a sample of sulfur tetrafluoride produces 4.43 g of fluorine and 1.87 g of sulfur. Calculate the mass of fluorine per gram of sulfur for each sample and show that these results are consistent with the law of multiple proportions.

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Textbook Question

Which statements are consistent with Dalton's atomic theory as it was originally stated? Why? a. Sulfur and oxygen atoms have the same mass. b. All cobalt atoms are identical. c. Potassium and chlorine atoms combine in a 1:1 ratio to form potassium chloride. d. Lead atoms can be converted into gold.

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Textbook Question

Which statements are consistent with Rutherford's nuclear theory as it was originally stated? Why? a. The volume of an atom is mostly empty space. b. The nucleus of an atom is small compared to the size of the atom. c. Neutral lithium atoms contain more neutrons than protons. d. Neutral lithium atoms contain more protons than electrons.

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Textbook Question

Which statements are inconsistent with Rutherford's nuclear theory as it was originally stated? Why? a. Since electrons are smaller than protons, and since a hydrogen atom contains only one proton and one electron, it must follow that the volume of a hydrogen atom is mostly due to the proton. b. A nitrogen atom has 7 protons in its nucleus and 7 electrons outside of its nucleus. c. A phosphorus atom has 15 protons in its nucleus and 150 electrons outside of its nucleus. d. The majority of the mass of a fluorine atom is due to its 9 electrons.

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Textbook Question

A chemist in an imaginary universe, where electrons have a different charge than they do in our universe, performs the Millikan oil drop experiment to measure the electron's charge. The charges of several drops are recorded here. What is the charge of the electron in this imaginary universe?

Drop # Charge

A –6.9×10–19 C

B –9.2×10–19 C

C –11.5×10–19 C

D –4.6×10–19 C

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