In this example question, it says we have 25 grams of dichloromethane, which is CH2Cl2, and it's dissolved in 125 grams of water. They say here, what is the mole fraction of dichloromethane? So we're going to start out with step one, and in step one we have to convert all the masses given to us into moles. Now to avoid rounding errors, make sure you have at least 4 decimal places when you convert to moles.
We're going to take the 25 grams of dichloromethane and we're going to say it's composed of 1 carbon, two hydrogens and two chlorines. Looking up their atomic masses from the periodic table and adding them together, we get a combined mass of 84.926 grams of CH2Cl2 for every one mole. So here the grams cancel out and then I'll get 0.2944 moles of our dichloromethane. Now take the 125 grams of water. At this point we've seen water so many times, you know that the mass of two hydrogens and one oxygen is 18.016 grams for every one mole of water. So again, our grams cancel out and now we're going to have 6.9383 moles for water.
Step 2, we're now going to place the mole component as the numerator of the mole fraction formula. So remember, the mole fraction of the mole component is based on who we're asked to find the mole fraction of, and we're asked to find the mole fraction of dichloromethane. So we're going to say here mole fraction equals the moles of dichloromethane and then determine the total value of moles added together and place it as the denominator of the mole fraction formula. So here we're going to take the 0.2944 moles of dichloromethane plus the moles of the water, and that'll give you my total moles, which is 7.2327.
So those moles here go on the bottom. So again, this is our total moles from adding up the moles of dichloromethane and water together. Now this is important. Your final answer should have no units because mole fraction is a unitless expression. That makes sense because the moles here would cancel out. So when we do that, we'll get as our final answer, 0.04070 as our mole fraction. This has four sig figs, just like 0.2944 moles had four sig figs.
So this is all we need to do when it comes to the mole fraction formula. Just remember who your mole component is. It's based on who you need to determine the mole fraction for. If you know that that goes as your numerator and then just total moles on the bottom as your denominator and you'll get your mole fraction at the end.