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Ch 18: A Macroscopic Description of Matter
Chapter 18, Problem 18

A diver 50 m deep in 10°C fresh water exhales a 1.0-cm-diameter bubble. What is the bubble's diameter just as it reaches the surface of the lake, where the water temperature is 20°C?

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Identify the initial conditions of the bubble when it is exhaled at a depth of 50 m: initial temperature (T1 = 10°C), initial pressure (P1), and initial volume (V1). Assume the initial volume is determined by the diameter of the bubble (1.0 cm).
Convert the initial temperature from Celsius to Kelvin by adding 273.15 to the Celsius value. This conversion is necessary for calculations involving the ideal gas law.
Apply the ideal gas law and the combined gas law to relate the initial conditions to the conditions at the surface. The combined gas law formula is (P1 * V1) / T1 = (P2 * V2) / T2, where P2 is the pressure at the surface (assumed to be 1 atmosphere), T2 is the temperature at the surface in Kelvin, and V2 is the final volume of the bubble.
Calculate the final volume of the bubble (V2) using the combined gas law. Since the pressure at the surface is less than at the depth, and the temperature is higher, expect the volume of the bubble to increase.
Determine the diameter of the bubble at the surface by converting the volume back to diameter. Use the formula for the volume of a sphere (V = (4/3)πr^3) to find the radius, and then double it to find the diameter.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, and temperature of a gas through the equation PV = nRT. In this scenario, as the bubble rises, the pressure decreases and the temperature changes, affecting its volume. This law helps us understand how the bubble expands as it ascends to the surface.
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Hydrostatic Pressure

Hydrostatic pressure is the pressure exerted by a fluid at equilibrium due to the force of gravity. At a depth of 50 m, the diver experiences significant pressure from the water above. As the bubble rises, the pressure decreases, which influences its volume and diameter according to the Ideal Gas Law.
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Thermal Expansion of Gases

Thermal expansion refers to the increase in volume of a gas as its temperature rises. In this case, as the bubble ascends from 10°C to 20°C, the increase in temperature will cause the gas inside the bubble to expand, leading to an increase in its diameter. This concept is crucial for calculating the final size of the bubble at the surface.
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