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Ch.21 - Organic Chemistry
Chapter 21, Problem 81a

Determine the products of each carboxylic acid reaction. a.
Chemical structure of a carboxylic acid reacting with an alcohol and sulfuric acid.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Carboxylic Acids

Carboxylic acids are organic compounds characterized by the presence of a carboxyl group (-COOH). They are known for their acidic properties due to the ability of the carboxyl group to donate a proton (H+). In reactions, carboxylic acids can undergo esterification, where they react with alcohols to form esters and water, often in the presence of an acid catalyst.
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Esterification Reaction

Esterification is a chemical reaction between a carboxylic acid and an alcohol, resulting in the formation of an ester and water. This reaction typically requires an acid catalyst, such as sulfuric acid, to proceed efficiently. The general equation for this reaction is: Carboxylic Acid + Alcohol ⇌ Ester + Water, highlighting the reversible nature of the process.
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Role of Sulfuric Acid

Sulfuric acid (H2SO4) serves as a strong acid catalyst in esterification reactions. It not only protonates the carboxylic acid, enhancing its electrophilicity, but also helps to remove water produced during the reaction, driving the equilibrium towards ester formation. This catalytic role is crucial for increasing the reaction rate and yield of the desired ester product.
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