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Ch.9 - Thermochemistry: Chemical Energy

Chapter 9, Problem 153b

(b) Use the data in Appendix B to calculate ΔH° for the reaction of potassium metal with water.

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hi everyone for this problem, we need to calculate the standard entropy change for conversion of liquid water to steam. So let's go ahead and get started. The first thing that we're going to want to do is write out our equation and so we have the conversion of liquid water to steam. And our equation for calculating the standard entropy change is that our standard entropy change of our reaction is equal to the sum of our products, minus the sum of our reactant. And we're going to need to look up the standard heats of formation for both liquid water and steam or water as gas. And those standard heats of formation are our standard heat of formation of liquid water Is going to equal negative 285.8 killer jewels Permal. And our standard heat of formation of steam or water as a gas is equal to -241. killer joules per mole. Okay, so now we have everything that we need to solve this problem. So let's plug in. So our standard entropy change of our reaction is going to equal. We have to pay attention to how many moles we have of everything. So our products, we have one product and we only have one mole of it. So we're going to multiply that one mole by its standard heat a formation. So for H 20 gas we said it's negative 241.8 kg joules per mole and we're going to minus our reactant. So we have one mole of H 20 liquid and its standard heat of formation is negative 285.8 killer jewels per more. Okay, so because we only have one mole of each, that makes this a little simple. So we're just going to have negative 241. kg joules per mole minus negative 285.8 kg jewels per mole. And this is going to give us our standard entropy change for our reaction. and so we're going to get a final answer of positive 40 for killer jewels per mole. And that is the answer to this problem. This is the standard entropy change for a conversion of liquid water to steam. That's the end of this problem. I hope this was helpful.
Related Practice
Textbook Question

Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are

(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(a) Balance both equations.

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Textbook Question

Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are

(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(b) How many kilograms of each substance is needed to neutralize a 1.000-gallon spill of pure acetic acid (density = 1.049 g/mL)?

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Textbook Question

(a) Write a balanced equation for the reaction of potassium metal with water.

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Textbook Question

(c) Assume that a chunk of potassium weighing 7.55 g is dropped into 400.0 g of water at 25.0 °C. What is the final temperature of the water if all the heat released is used to warm the water?

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Textbook Question

(d) What is the molarity of the KOH solution prepared in part (c), and how many milliliters of 0.554 M H2SO4 are required to neutralize it?

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Textbook Question
Hydrazine, a component of rocket fuel, undergoes combus- tion to yield N2 and H2O: N2H41l2 + O21g2 S N21g2 + 2 H2O1l2 (b) Use the following information to set up a Hess's law cycle, and then calculate ΔH° for the combustion reac- tion. You will need to use fractional coefficients for some equations. 2 NH31g2 + 3 N2O1g2 S 4 N21g2 + 3 H2O1l2 ΔH° = - 1011.2 kJ N2O1g2 + 3 H21g2 S N2H41l2 + H2O1l2 ΔH° = - 317.2 kJ 4 NH31g2 + O21g2 S 2 N2H41l2 + 2 H2O1l2 ΔH° = - 286.0 kJ H2O1l2 ΔH°f = - 285.8 kJ>mol
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