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Ch.9 - Thermochemistry: Chemical Energy
Chapter 9, Problem 152a

Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are
(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(a) Balance both equations.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Neutralization

Acid-base neutralization is a chemical reaction where an acid reacts with a base to produce water and a salt. In this context, acetic acid (CH₃CO₂H) acts as the acid, while sodium carbonate (Na₂CO₃) and sodium bicarbonate (NaHCO₃) serve as the bases. The reaction results in the formation of sodium acetate (CH₃CO₂Na), carbon dioxide (CO₂), and water (H₂O), illustrating the fundamental principle of neutralization.
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Balancing Chemical Equations

Balancing chemical equations involves ensuring that the number of atoms for each element is the same on both sides of the equation. This is crucial for obeying the law of conservation of mass, which states that matter cannot be created or destroyed in a chemical reaction. To balance the equations provided, coefficients are adjusted to achieve equal numbers of each type of atom in the reactants and products.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on balanced equations. It allows chemists to predict the amounts of substances consumed and produced in a reaction. In the context of the given equations, stoichiometry helps determine the proportions of acetic acid, sodium carbonate, and sodium bicarbonate needed for complete neutralization, ensuring efficient and safe handling of acid spills.
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Related Practice
Textbook Question
Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g. (d) The enthalpy of combustion for methyl tert-butyl ether is ΔH° combustion = -3368.7 kJ>mol. What is its standard enthalpy of enthalpy of formation, ΔH°f?
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Textbook Question

Phosgene, COCl2(g), is a toxic gas used as an agent of warfare in World War I. (b) Using the table of bond dissociation energies (Table 9.3) and the value ΔH°f = 716.7 kJ/mol for C(g), estimate ΔH°f for COCl2(g) at 25 °C. Compare your answer to the actual ΔH°f given in Appendix B, and explain why your calculation is only an estimate.

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Textbook Question
Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are 112 CH3CO2H1l2 + Na2CO31s2 S CH3CO2Na1aq2 + CO21g2 + H2O1l2 122 CH3CO2H1l2 + NaHCO31s2 CH3CO2Na1aq2 + CO21g2 + H2O1l2 (c) How much heat in kilojoules is absorbed or liberated in each reaction? See Appendix B for standard heats of for- mation; ΔH°f = - 726.1 kJ>mol for CH3CO2 Na(aq).
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Textbook Question

Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are

(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(b) How many kilograms of each substance is needed to neutralize a 1.000-gallon spill of pure acetic acid (density = 1.049 g/mL)?

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Textbook Question

(a) Write a balanced equation for the reaction of potassium metal with water.

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Textbook Question

(b) Use the data in Appendix B to calculate ΔH° for the reaction of potassium metal with water.

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