Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are
(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(a) Balance both equations.
Verified Solution
Key Concepts
Acid-Base Neutralization
Balancing Chemical Equations
Stoichiometry
Phosgene, COCl2(g), is a toxic gas used as an agent of warfare in World War I. (b) Using the table of bond dissociation energies (Table 9.3) and the value ΔH°f = 716.7 kJ/mol for C(g), estimate ΔH°f for COCl2(g) at 25 °C. Compare your answer to the actual ΔH°f given in Appendix B, and explain why your calculation is only an estimate.
Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are
(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)
(b) How many kilograms of each substance is needed to neutralize a 1.000-gallon spill of pure acetic acid (density = 1.049 g/mL)?
(a) Write a balanced equation for the reaction of potassium metal with water.
(b) Use the data in Appendix B to calculate ΔH° for the reaction of potassium metal with water.