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Ch.9 - Thermochemistry: Chemical Energy
Chapter 9, Problem 153c

(c) Assume that a chunk of potassium weighing 7.55 g is dropped into 400.0 g of water at 25.0 °C. What is the final temperature of the water if all the heat released is used to warm the water?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Heat Transfer

Heat transfer is the process by which thermal energy moves from one object or substance to another due to a temperature difference. In this scenario, the heat released by the potassium as it reacts with water will be absorbed by the water, leading to an increase in its temperature. Understanding this concept is crucial for calculating the final temperature of the water.
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Heat Capacity

Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of one gram of a substance by one degree Celsius. Each substance has a unique specific heat capacity, which influences how much its temperature will change when heat is added or removed. For water, the specific heat capacity is approximately 4.18 J/g°C, which is essential for determining how much the temperature of the water will increase in response to the heat from the potassium.
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Calorimetry

Calorimetry is the science of measuring the heat of chemical reactions or physical changes. In this problem, calorimetry principles can be applied to calculate the final temperature of the water by equating the heat lost by the potassium to the heat gained by the water. This involves using the formula Q = mcΔT, where Q is the heat exchanged, m is the mass, c is the specific heat capacity, and ΔT is the change in temperature.
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Related Practice
Textbook Question

Acid spills are often neutralized with sodium carbonate or sodium hydrogen carbonate. For neutralization of acetic acid, the unbalanced equations are

(1) CH3CO2H(l) + Na2CO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(2) CH3CO2H(l) + NaHCO3(s) → CH3CO2Na(aq) + CO2(g) + H2O(l)

(b) How many kilograms of each substance is needed to neutralize a 1.000-gallon spill of pure acetic acid (density = 1.049 g/mL)?

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Textbook Question

(a) Write a balanced equation for the reaction of potassium metal with water.

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Textbook Question

(b) Use the data in Appendix B to calculate ΔH° for the reaction of potassium metal with water.

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Textbook Question

(d) What is the molarity of the KOH solution prepared in part (c), and how many milliliters of 0.554 M H2SO4 are required to neutralize it?

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Textbook Question
Hydrazine, a component of rocket fuel, undergoes combus- tion to yield N2 and H2O: N2H41l2 + O21g2 S N21g2 + 2 H2O1l2 (b) Use the following information to set up a Hess's law cycle, and then calculate ΔH° for the combustion reac- tion. You will need to use fractional coefficients for some equations. 2 NH31g2 + 3 N2O1g2 S 4 N21g2 + 3 H2O1l2 ΔH° = - 1011.2 kJ N2O1g2 + 3 H21g2 S N2H41l2 + H2O1l2 ΔH° = - 317.2 kJ 4 NH31g2 + O21g2 S 2 N2H41l2 + 2 H2O1l2 ΔH° = - 286.0 kJ H2O1l2 ΔH°f = - 285.8 kJ>mol
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Textbook Question
Reaction of gaseous fluorine with compound X yields a sin- gle product Y, whose mass percent composition is 61.7% F and 38.3% Cl. (c) Calculate ΔH° for the synthesis of Y using the following information: 2 CIF1g2 + O21g2 S Cl2O1g2 + OF21g2 ΔH° = + 205.4 kJ 2 CIF31l2 + 2 O21g2 S Cl2O1g2 + 3 OF21g2 ΔH° = + 532.8 kJ OF21g2 ΔH°f = + 24.5 kJ>mol
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