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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 38

Assume that an aqueous solution of a cation, represented as a red sphere, is allowed to mix with a solution of an anion, represented as a yellow sphere. Three possible outcomes are represented by boxes (1)–(3): Two boxes showing blue spheres for cations and green spheres for anions in aqueous solutions.
Which outcome corresponds to each of the following reactions? (a) 2 Na+(aq) + CO32-(aq) S (b) Ba2+(aq) + CrO42-(aq) S (c) 2 Ag+(aq) + SO32-(aq) S

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ionic Compounds and Precipitation Reactions

Ionic compounds are formed from the electrostatic attraction between cations and anions. In aqueous solutions, certain combinations of ions can lead to precipitation reactions, where insoluble ionic compounds form and separate from the solution. Understanding the solubility rules helps predict whether a precipitate will form when two ionic solutions are mixed.
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Solubility Rules

Solubility rules are guidelines that help predict the solubility of ionic compounds in water. For example, most alkali metal salts and nitrates are soluble, while many sulfates and carbonates are not. These rules are essential for determining the outcomes of reactions involving ionic compounds, particularly in predicting which combinations will yield a solid precipitate.
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Chemical Equation Representation

Chemical equations represent the reactants and products in a chemical reaction. In the context of precipitation reactions, the equations show the ions involved and the resulting solid. Understanding how to balance these equations and identify the states of matter (solid, liquid, gas, aqueous) is crucial for accurately describing the outcomes of the reactions presented in the question.
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Related Practice
Textbook Question
The most strongly reducing elements are listed at the top of the partial activity series table provided. Use the activity series to predict which reaction will occur. (LO 4.20) (a) (b) (c) (d)

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Textbook Question
The concentration of a solution of potassium permanganate, KMnO4, can be determined by titration with a known amount of oxalic acid, H2C2O4, according to the following equation: What is the concentration of a KMnO4 solution if 22.35 mL reacts with 0.5170 g of oxalic acid? (LO 4.22) (a) 0.6423 M (b) 0.1028 M (c) 0.4161 M (d) 0.2569 M
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Textbook Question

Box (a) represents 1.0 mL of a solution of particles at a given concentration. Which of the boxes (b)–(d) represents 1.0 mL of the solution that results after (a) has been diluted by doubling the volume of its solvent? (a)

(b)

(c)

(d)

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Textbook Question
Assume that an aqueous solution of a cation, represented as a blue sphere, is allowed to mix with a solution of an anion, repre-sented as a red sphere, and that the following result is obtained: Which combinations of cation and anion, chosen from the fol-lowing lists, are compatible with the observed results? Explain Cations: Na+, Ca2+, Ag+, Ni2+ Anions: Cl-, CO3 2-, CrO4 2-, NO3
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Textbook Question
The following pictures represent aqueous solutions of three acids HA (A = X, Y, or Z), with surrounding water mol-ecules omitted for clarity. Which of the three is the strongest acid, and which is the weakest?

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Textbook Question
Assume that an aqueous solution of OH-, represented as a blue sphere, is allowed to mix with a solution of an acid HnA, represented as a red sphere. Three possible outcomes are depicted by boxes (1)–(3), where the green spheres represent An-, the anion of the acid: Which outcome corresponds to each of the following reactions? (a) (b) (c)
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