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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 15

The concentration of a solution of potassium permanganate, KMnO4, can be determined by titration with a known amount of oxalic acid, H2C2O4, according to the following equation: What is the concentration of a KMnO4 solution if 22.35 mL reacts with 0.5170 g of oxalic acid? (LO 4.22) (a) 0.6423 M (b) 0.1028 M (c) 0.4161 M (d) 0.2569 M

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. It involves the gradual addition of a titrant of known concentration to a solution containing the analyte until the reaction reaches its endpoint, which is often indicated by a color change. In this case, potassium permanganate (KMnO4) acts as the titrant reacting with oxalic acid (H2C2O4).
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the relationships between the amounts of substances involved in the reaction. For the titration of KMnO4 with oxalic acid, the stoichiometric coefficients from the balanced equation will be essential to relate the moles of oxalic acid to the moles of KMnO4.
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Molarity

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is expressed in moles per liter (M). To find the concentration of the KMnO4 solution, one must calculate the moles of oxalic acid used in the reaction and then use the stoichiometry of the reaction to find the corresponding moles of KMnO4, which can then be converted to molarity using the volume of the KMnO4 solution.
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Related Practice
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Assign oxidation numbers to each atom in Borax, Na2B4O7, a mineral used in laundry detergent. (LO 4.18)
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Identify the element that gets oxidized and the oxidizing agent in the reaction. (LO 4.19) (a) (b) (c) (d)
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The most strongly reducing elements are listed at the top of the partial activity series table provided. Use the activity series to predict which reaction will occur. (LO 4.20) (a) (b) (c) (d)

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Textbook Question

Box (a) represents 1.0 mL of a solution of particles at a given concentration. Which of the boxes (b)–(d) represents 1.0 mL of the solution that results after (a) has been diluted by doubling the volume of its solvent? (a)

(b)

(c)

(d)

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Textbook Question
Assume that an aqueous solution of a cation, represented as a red sphere, is allowed to mix with a solution of an anion, represented as a yellow sphere. Three possible outcomes are represented by boxes (1)–(3):

Which outcome corresponds to each of the following reactions? (a) 2 Na+(aq) + CO32-(aq) S (b) Ba2+(aq) + CrO42-(aq) S (c) 2 Ag+(aq) + SO32-(aq) S
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Textbook Question
Assume that an aqueous solution of a cation, represented as a blue sphere, is allowed to mix with a solution of an anion, repre-sented as a red sphere, and that the following result is obtained: Which combinations of cation and anion, chosen from the fol-lowing lists, are compatible with the observed results? Explain Cations: Na+, Ca2+, Ag+, Ni2+ Anions: Cl-, CO3 2-, CrO4 2-, NO3
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