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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 12

Assign oxidation numbers to each atom in Borax, Na2B4O7, a mineral used in laundry detergent. (LO 4.18)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation Numbers

Oxidation numbers are assigned to atoms in a compound to indicate the degree of oxidation or reduction of each atom. They help in understanding electron transfer in redox reactions. The rules for assigning oxidation numbers include that the oxidation number of an element in its elemental form is zero, and for monoatomic ions, it equals the charge of the ion.
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Oxidation Numbers

Polyatomic Ions

Borax contains the polyatomic ion B4O7^2-, which consists of boron and oxygen atoms. Understanding the structure and charge of polyatomic ions is crucial for assigning oxidation numbers correctly. Each atom within the polyatomic ion contributes to the overall charge, which must be balanced with the oxidation numbers assigned to the other elements in the compound.
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Balancing Charges

When assigning oxidation numbers, it is essential to ensure that the sum of the oxidation numbers equals the overall charge of the compound. In the case of Borax, Na2B4O7, the sodium ions (Na+) contribute a +2 charge, which must be balanced by the oxidation numbers of the boron and oxygen atoms in the B4O7^2- ion. This balancing act is key to accurately determining the oxidation states.
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Related Practice
Textbook Question
When 75.0 mL of a 0.100 M lead(II) nitrate solution is mixed with 100.0 mL of a 0.190 M potassium iodide solu-tion, a yellow-orange precipitate of lead(II) iodide is formed. What is the mass in grams of lead(II) iodide formed? Assume the reaction goes to completion. (LO 4.11, 4.15) (a) 1.729 g (b) 3.458 g (c) 4.380 g (d) 8.760 g
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Textbook Question
What volume of 0.250 M HCl is needed to react completely with 25.00 mL of 0.375 M Na2CO3? (LO 4.15) (a) 75.0 mL (b) 18.8 mL (c) 37.5 mL (d) 33.3 mL
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Textbook Question
Succinic acid, an intermediate in the metabolism of food molecules, has a molecular weight of 118.1. When 1.926 g of succinic acid was dissolved in water and titrated, 65.20 mL of 0.5000 M NaOH solution was required to neutralize the acid. How many acidic hydrogens are there in a mol-ecule of succinic acid? (LO 4.16) (a) 1 (b) 2 (c) 3 (d) 4
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Textbook Question
Identify the element that gets oxidized and the oxidizing agent in the reaction. (LO 4.19) (a) (b) (c) (d)
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Textbook Question
The most strongly reducing elements are listed at the top of the partial activity series table provided. Use the activity series to predict which reaction will occur. (LO 4.20) (a) (b) (c) (d)

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Textbook Question
The concentration of a solution of potassium permanganate, KMnO4, can be determined by titration with a known amount of oxalic acid, H2C2O4, according to the following equation: What is the concentration of a KMnO4 solution if 22.35 mL reacts with 0.5170 g of oxalic acid? (LO 4.22) (a) 0.6423 M (b) 0.1028 M (c) 0.4161 M (d) 0.2569 M
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