Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 40
The following pictures represent aqueous solutions of three acids HA (A = X, Y, or Z), with surrounding water mol-ecules omitted for clarity. Which of the three is the strongest acid, and which is the weakest?
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Textbook Question
Box (a) represents 1.0 mL of a solution of particles at a given concentration. Which of the boxes (b)–(d) represents 1.0 mL of the solution that results after (a) has been diluted by doubling the volume of its solvent? (a)
(b)
(c)
(d)
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Textbook Question
Assume that an aqueous solution of a cation, represented as a red sphere, is allowed to mix with a solution of an anion, represented as a yellow sphere. Three possible outcomes are represented by boxes (1)–(3):
Which outcome corresponds to each of the following reactions?
(a) 2 Na+(aq) + CO32-(aq) S
(b) Ba2+(aq) + CrO42-(aq) S
(c) 2 Ag+(aq) + SO32-(aq) S
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Textbook Question
Assume that an aqueous solution of a cation, represented as a blue sphere, is allowed to mix with a solution of an anion, repre-sented as a red sphere, and that the following result is obtained:
Which combinations of cation and anion, chosen from the fol-lowing lists, are compatible with the observed results? Explain
Cations: Na+, Ca2+, Ag+, Ni2+
Anions: Cl-, CO3
2-, CrO4 2-, NO3
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Textbook Question
Assume that an aqueous solution of OH-, represented as a blue sphere, is allowed to mix with a solution of an acid HnA, represented as a red sphere. Three possible outcomes are depicted by boxes (1)–(3), where the green spheres represent An-, the anion of the acid:
Which outcome corresponds to each of the following reactions?
(a)
(b)
(c)
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Textbook Question
The concentration of an aqueous solution of NaOCl (sodium hypochlorite; the active ingredient in household bleach) can be determined by a redox titration with iodide ion in acidic solution:
Assume that the blue spheres in the buret represent I-ions, the red spheres in the flask represent OCl-ions, the con-centration of the I-ions in the buret is 0.120 M, and the volumes in the buret and the flask are identical. What is the concentration of NaOCl in the flask? What percentage of the I-solution in the buret must be added to the flask to react with all the OCl-ions?
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Textbook Question
Classify each of the following unbalanced half-reactions as either an oxidation or a reduction. (a) HClO(aq) → Cl2(g)
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