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Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 29

What is the vapor pressure of SiCl4 in mm Hg at 30.0 °C? (See Problem 11.27.)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Vapor Pressure

Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid phase at a given temperature. It reflects the tendency of particles to escape from the liquid or solid state into the gas phase. Higher temperatures generally increase vapor pressure, as more molecules have sufficient energy to overcome intermolecular forces.
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Temperature and Vapor Pressure Relationship

The relationship between temperature and vapor pressure is described by the Clausius-Clapeyron equation, which shows that as temperature increases, vapor pressure also increases. This is due to the increased kinetic energy of molecules at higher temperatures, leading to a greater number of molecules transitioning into the vapor phase. Understanding this relationship is crucial for predicting vapor pressures at different temperatures.
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SiCl4 Properties

Silicon tetrachloride (SiCl4) is a chemical compound that exhibits specific physical properties, including its vapor pressure at various temperatures. Knowing the vapor pressure of SiCl4 at a given temperature, such as 30.0 °C, is essential for applications in chemical processes and safety assessments. Reference data or experimental values are often used to determine these properties.
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Physical Properties
Related Practice
Textbook Question
The chemical structure for oleic acid, the primary component of olive oil, is shown. Explain why olive oil has a higher vis- cosity than water.
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Textbook Question
The viscosity of water at 20 °C is 1.00 * 10-3 1N • s>m2 2 higher than dimethyl sulfide 31CH322 S4 2.8 * 10-4 1N • s>m2 2. Explain the difference in viscosity based on chemical structure.
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Textbook Question
Assume that you have a sample of gas at 350 K in a sealed container, as represented in (a). Which of the drawings (b)–(d) represents the gas after the temperature is lowered from 350 K to 150 K? The boiling point of the gas is 90 K.

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Textbook Question
Dichloromethane, CH2Cl2, is an organic solvent used for removing caffeine from coffee beans. The following table gives the vapor pressure of dichloromethane at various tem- peratures. Fill in the rest of the table, and use the data to plot curves of Pvap versus T and ln Pvap versus 1/T.
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Textbook Question
The following diagram shows a close-up view of part of the vapor-pressure curves for a solvent (red curve) and a solution of the solvent with a second liquid (green curve). Is the second liquid more volatile or less volatile than the solvent?

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Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for two solutions of equal con- centration, one containing a nonvolatile solute and the other containing a volatile solute whose vapor pressure at a given temperature is approximately half that of the pure solvent.

(d) Based on your drawing, what is the approximate normal boiling point of the pure solvent?
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