Skip to main content
Ch.11 - Liquids & Phase Changes

Chapter 11, Problem 31

The following diagram shows a close-up view of part of the vapor-pressure curves for a solvent (red curve) and a solution of the solvent with a second liquid (green curve). Is the second liquid more volatile or less volatile than the solvent?

Verified Solution
Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
538
views
Was this helpful?

Video transcript

Hello everyone today. We have the following question. The vapor pressure curve diagram shown below shows how the vapor pressure for a pure liquid A. Which is the blue curve changes with temperature. Another curve from the diagram, which is the red curve is for the solution of another liquid. Be in liquid A. Is liquid be more volatile or less volatile than liquid A. So first with vapor pressure this curve, the vapor pressure curve is going to essentially just show us how the vapor pressure changes with temperature changes with temperature. And so the blue line here simply just shows that we have a direct or a direct proportion relationship. So the vapor pressure of liquid A. Is going to increase with an increase in the temperature. And so we can also see that this red line here is a lot higher than this blue light here. This means that the vapor pressure of the solution is higher than that of pure liquid A. And as a result this higher vapor pressure is a result of the vapor pressure of B at a particular temperature being higher than that of liquid A. So we can say that due to a higher vapor pressure of liquid B. That is in a. The solution has a higher vapor pressure than pure liquid A. So therefore we can conclude that liquid B. Is more volatile than liquid A. And with that we have answered the question overall. I hope that this helped and until next time
Related Practice
Textbook Question
Assume that you have a sample of gas at 350 K in a sealed container, as represented in (a). Which of the drawings (b)–(d) represents the gas after the temperature is lowered from 350 K to 150 K? The boiling point of the gas is 90 K.

524
views
Textbook Question
What is the vapor pressure of SiCl4 in mm Hg at 30.0 °C? (See Problem 11.27.)
720
views
Textbook Question
Dichloromethane, CH2Cl2, is an organic solvent used for removing caffeine from coffee beans. The following table gives the vapor pressure of dichloromethane at various tem- peratures. Fill in the rest of the table, and use the data to plot curves of Pvap versus T and ln Pvap versus 1/T.
699
views
Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for two solutions of equal con- centration, one containing a nonvolatile solute and the other containing a volatile solute whose vapor pressure at a given temperature is approximately half that of the pure solvent.

(d) Based on your drawing, what is the approximate normal boiling point of the pure solvent?
679
views
Textbook Question
Choose any two temperatures and corresponding vapor pressures in the table given in Problem 11.30, and use those values to calculate ΔHvap for dichloromethane in kJ/mol. How does the value you calculated compare to the value you read from your plot in Problem 11.32?
674
views
Textbook Question
The dipole moment of methanol is m = 1.70 D. Use arrows to indicate the direction in which electrons are displaced.

1522
views