Chapter 17, Problem 118
Fluoridation of drinking water is employed in many places to aid in the prevention of tooth decay. Typically. the Fion concentration is adjusted to about 1 ppm. Some water supplies are also 'hard'; that is, they contain certain cations such as Ca2 + that interfere with the action of soap. Consider a case where the concentration of Ca2 + is 8 ppm. Could a precipitate of CaF2 form under these conditions? (Make any necessary approximations.)
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What is the pH at 25 C of water saturated with CO2 at a partial pressure of 1.10 atm? The Henry's law constant for CO2 at 25 C is 3.1 * 10-2 mol>L@atm.
The osmotic pressure of a saturated solution of strontium sulfate at 25 C is 21 torr. What is the solubility product of this salt at 25 C?
A concentration of 10–100 parts per billion (by mass) of Ag+ is an effective disinfectant in swimming pools. However, if the concentration exceeds this range, the Ag+ can cause adverse health effects. One way to maintain an appropriate concentration of Ag+ is to add a slightly soluble salt to the pool. Using Ksp values from Appendix D, calculate the equilibrium concentration of Ag+ in parts per billion that would exist in equilibrium with (c) AgI.
Baking soda (sodium bicarbonate, NaHCO3) reacts with acids in foods to form carbonic acid 1H2CO32, which in turn decomposes to water and carbon dioxide gas. In a cake batter, the CO21g2 forms bubbles and causes the cake to rise. (a) A rule of thumb in baking is that 1/2 teaspoon of baking soda is neutralized by one cup of sour milk. The acid component in sour milk is lactic acid, CH3CH1OH2COOH. Write the chemical equation for this neutralization reaction.
Baking soda (sodium bicarbonate, NaHCO3) reacts with acids in foods to form carbonic acid 1H2CO32, which in turn decomposes to water and carbon dioxide gas. In a cake batter, the CO21g2 forms bubbles and causes the cake to rise. (c) If 1/2 teaspoon of baking soda is indeed completely neutralized by the lactic acid in sour milk, calculate the volume of carbon dioxide gas that would be produced at 1 atm pressure, in an oven set to 350 F.
In nonaqueous solvents, it is possible to react HF to create H2F+. Which of these statements follows from this observation? (a) HF can act like a strong acid in nonaqueous solvents, (b) HF can act like a base in nonaqueous solvents, (c) HF is thermodynamically unstable, (d) There is an acid in the nonaqueous medium that is a stronger acid than HF.