Chapter 15, Problem 62c
Consider the reaction 4 NH3(π) + 5 O2(π) β 4 NO(π) + 6 H2O(π), Ξπ» = β904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (c) decrease [O2]
Video transcript
At 80Β°C, πΎπ = 1.87Γ10β3 for the reaction PH3BCl3(π ) β PH3(π) + BCl3(π) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached. (b) If the flask has a volume of 0.250 L, what is the minimum mass of PH3BCl3(π ) that must be added to the flask to achieve equilibrium?
At 25Β°C, the reaction CaCrO4(π ) β Ca2+(ππ) + CrO42β(ππ) has an equilibrium constant πΎπ = 7.1Γ10β4. What are the equilibrium concentrations of Ca2+ and CrO42β in a saturated solution of CaCrO4?
Consider the following equilibrium, for which Ξπ»<0
2 SO2(π) + O2(π) β 2 SO3(π)
(f) How will each of the following changes affect an equilibrium mixture of the three gases: SO3(π) is removed from the system?
Consider the reaction 4 NH3(π) + 5 O2(π) β 4 NO(π) + 6 H2O(π), Ξπ» = β904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (d) decrease the volume of the container in which the reaction occurs
Consider the reaction 4 NH3(π) + 5 O2(π) β 4 NO(π) + 6 H2O(π), Ξπ» = β904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (e) add a catalyst
Consider the reaction 4 NH3(π) + 5 O2(π) β 4 NO(π) + 6 H2O(π), Ξπ» = β904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (f) increase temperature.