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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 58

At 25Β°C, the reaction CaCrO4(𝑠) β‡Œ Ca2+(π‘Žπ‘ž) + CrO42βˆ’(π‘Žπ‘ž) has an equilibrium constant 𝐾𝑐 = 7.1Γ—10βˆ’4. What are the equilibrium concentrations of Ca2+ and CrO42βˆ’ in a saturated solution of CaCrO4?

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Hello everyone today. We are being given the following problem and asks to solve for it. It says the equilibrium constant K. C. Of the following reaction at 25 degrees Celsius is 8.6 times 10 to the negative fifth in a saturated solution of this magnesium oxalate, calculate the the equilibrium concentrations of both magnesium and oxalic acid obsolete. So the first thing they don't want to do is we want to know our K. C. Expression So we have Casey and when right in this case the expression we're going to write the concentration of our products and the numerator over the concentration of our reactant in the denominator. And so we're also going to only want to pay attention to gasses. So with Casey expression you only pay attention to the gasses in writing this out. We're gonna start with our first reactant which is magnesium. So we're going to have MG two plus in brackets. And we're going to multiply the second reactant which is oxalate, C 2042 - also in Brackets. And since we said that we only pay attention to gasses and not solids, we are not going to write our magnesium oxalate in this case the expression and so continue on to this. Since we don't know the concentrations of magnesium or oxalate, we can simply substitute them for X. So we're going to have X times X. And then we plug in our K. C. Value of 8.6 times 10 to the negative fifth. That will equal X squared When we square both sides, we get that X. is equal to 9.3 times 10 to the negative third, and that is also going to be equal to our concentrations of magnesium two plus as well as our concentration of oxalate. I hope this helped, and until next time.
Related Practice
Textbook Question

At 218Β°C, 𝐾𝑐 = 1.2Γ—10βˆ’4 for the equilibrium NH4SH(𝑠) β‡Œ NH3(𝑔) + H2S(𝑔) Calculate the equilibrium concentrations of NH3 and H2S if a sample of solid NH4SH is placed in a closed vessel at 218Β°C and decomposes until equilibrium is reached.

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Textbook Question

At 80Β°C, 𝐾𝑐 = 1.87Γ—10βˆ’3 for the reaction PH3BCl3(𝑠) β‡Œ PH3(𝑔) + BCl3(𝑔) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached.

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Textbook Question

At 80Β°C, 𝐾𝑐 = 1.87Γ—10βˆ’3 for the reaction PH3BCl3(𝑠) β‡Œ PH3(𝑔) + BCl3(𝑔) (a) Calculate the equilibrium concentrations of PH3 and BCl3 if a solid sample of PH3BCl3 is placed in a closed vessel at 80Β°C and decomposes until equilibrium is reached. (b) If the flask has a volume of 0.250 L, what is the minimum mass of PH3BCl3(𝑠) that must be added to the flask to achieve equilibrium?

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Textbook Question

Consider the following equilibrium, for which Δ𝐻<0

2 SO2(𝑔) + O2(𝑔) β‡Œ 2 SO3(𝑔)

(f) How will each of the following changes affect an equilibrium mixture of the three gases: SO3(𝑔) is removed from the system?

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Textbook Question

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (c) decrease [O2]

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Textbook Question

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (d) decrease the volume of the container in which the reaction occurs

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