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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 62e

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (e) add a catalyst

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Hi everyone for this problem. It reads consider the following reaction, chlorine nitrate plus nitric oxide yields nitrogen dioxide plus iodine. Isocyanate, adding a catalyst would increase the yield of iodine. Isocyanate at equilibrium. Is this statement correct? So this is the question that we want to answer here and we have a system that's at equilibrium. So for this problem we're dealing with lush outliers principle and this principle tells us if a stress is put on a system at equilibrium, the system will try to shift or adjust to minimize the effect of that stress. So the stress that's being referred to here is the addition of a catalyst. So let's just recall what are some of the stressors that can be put on a system that's at equilibrium. That can increase the yield of a deny society. So one of the stressors is change in concentration. Okay, so this is a change in concentration of products or react ints. That is one type of stressor. Another type of stressor is change in pressure, which leads to a change in volume because these are inversely proportional in our last type of stressor is a change in temperature. So here we see catalyst, a catalyst is something that increases the rate of a reaction but it has no effect on the position of the equilibrium. So for this question is this statement correct adding a catalyst would increase the yield of iodine or of excuse me? Yes. iodine ice assign it. The answer is going to be no. Okay, No, because we're dealing with a catalyst and this catalyst would only affect the rate of the reaction, not the position of the equilibrium. So this is the answer to this problem. I hope this was helpful.
Related Practice
Textbook Question

Consider the following equilibrium, for which Δ𝐻<0

2 SO2(𝑔) + O2(𝑔) β‡Œ 2 SO3(𝑔)

(f) How will each of the following changes affect an equilibrium mixture of the three gases: SO3(𝑔) is removed from the system?

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Textbook Question

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (c) decrease [O2]

295
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Textbook Question

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (d) decrease the volume of the container in which the reaction occurs

487
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Textbook Question

Consider the reaction 4 NH3(𝑔) + 5 O2(𝑔) β‡Œ 4 NO(𝑔) + 6 H2O(𝑔), Δ𝐻 = βˆ’904.4 kJ Does each of the following increase, decrease, or leave unchanged the yield of NO at equilibrium? (f) increase temperature.

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Textbook Question

Consider the following equilibrium between oxides of nitrogen 3 NO(g) β‡Œ NO2(g) + N2O(g) (a) Use data in Appendix C to calculate Ξ”HΒ° for this reaction.

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Textbook Question

Methanol (CH3OH) can be made by the reaction of CO with H2: CO(𝑔) + 2 H2(𝑔) β‡Œ CH3OH(𝑔) (a) Use thermochemical data in Appendix C to calculate Ξ”HΒ° for this reaction.

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