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Ch.13 - Properties of Solutions

Chapter 13, Problem 64

The vapor pressure of pure water at 60 °C is 149 torr. The vapor pressure of water over a solution at 60 °C containing equal numbers of moles of water and ethylene glycol (a nonvolatile solute) is 67 torr. Is the solution ideal according to Raoult's law?

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Hello everyone today. We are being given the following problem and asked us to solve for it. It says the vapor pressure of a pure volatile solvent at 45 degrees Celsius is 47. Tour. A non volatile saw you is added to the solvent in such an amount that the mole fraction of the saw you in. The resulting solution is 470.15. The vapor pressure of the solution is found to be 2 95. Tour Using routes law identified a solution as ideal or non ideal. The first thing I wanna do is we want to calculate the vapor pressure of the solution. We can do that by using this equation here. We can see that the pressure Is equal to the mole fraction times the partial pressure of the solutions. And so we need the mole fraction of the solvent here. We know that the mole fraction of the of the is .15. And so to find the mole fraction of the solvent. We simply take one. We subtract it by that .15 giving us .85. We can now plug in our values, we can plug in our 0.85 for our mole fraction there And then we can multiply that by the tour that we have for the solvent which is 347. By doing that we get the pressure is equal to 295. Tour as you can see the calculated vapor pressure as we have here is the same as the experimentally designed one as in the question stem and so therefore we can say that this solution is I deal I hope this helped until next time.
Related Practice
Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (a) The freezing point of the solution is unchanged by addition of the solvent.

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Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (b) The solid that forms as the solution freezes is nearly pure solute.

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Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (d) The boiling point of the solution increases in proportion to the concentration of the solute.

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Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (a) What is the mole fraction of ethanol in the solution?

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Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (b) Assuming ideal solution behavior, what is the vapor pressure of the solution at 63.5 °C?

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Textbook Question

At 20 °C, the vapor pressure of benzene (C6H6) is 75 torr, and that of toluene (C7H8) is 22 torr. Assume that benzene and toluene form an ideal solution. (b) What is the mole fraction of benzene in the vapor above the solution described in part (a)?

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