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Ch.13 - Properties of Solutions

Chapter 13, Problem 62d

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (d) The boiling point of the solution increases in proportion to the concentration of the solute.

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Hey everyone, we're asked to identify the following statement as true or false. The boiling point of a solution prepared by dissolving a non volatile salute in a volatile solvent is lower than the boiling point of the pure solvent. Now we've learned that the solute particles will distribute evenly in our solution and these solute particles will replace the solvent molecules on the surface of the solution. So this means our solution will have a smaller number of solvent particles on our surface than our pure solvent. And since we have evaporation taking place, this means that our vapor pressure of our solution will be less than our vapor pressure of our pure solvent. Now relating this to our boiling point, we know that our boiling point is inversely proportional to our vapor pressure. So since our vapor pressure of our solution is less than our vapor pressure of our pure solvent, this means our boiling point of our solution must be higher than the boiling point of our pure solvent. And because of this relationship, our statement here is going to be incorrect and we can fix this statement by changing this term into higher. So I hope that made sense and let us know if you have any questions
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Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (a) The freezing point of the solution is unchanged by addition of the solvent.

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Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (b) The solid that forms as the solution freezes is nearly pure solute.

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Textbook Question
The vapor pressure of pure water at 60 °C is 149 torr. The vapor pressure of water over a solution at 60 °C containing equal numbers of moles of water and ethylene glycol (a nonvolatile solute) is 67 torr. Is the solution ideal according to Raoult's law?
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Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (a) What is the mole fraction of ethanol in the solution?

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Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (b) Assuming ideal solution behavior, what is the vapor pressure of the solution at 63.5 °C?

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