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Ch.13 - Properties of Solutions
Chapter 13, Problem 65

(a) Calculate the vapor pressure of water above a solution prepared by adding 22.5 g of lactose (C12H22O11) to 200.0 g of water at 338 K. (Vapor–pressure data for water are given in Appendix B.)

Verified step by step guidance
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Step 1: Determine the molar mass of lactose (C_{12}H_{22}O_{11}) by adding the atomic masses of its constituent elements: 12 carbon atoms, 22 hydrogen atoms, and 11 oxygen atoms.
Step 2: Calculate the number of moles of lactose using the formula: \( \text{moles of lactose} = \frac{\text{mass of lactose}}{\text{molar mass of lactose}} \).
Step 3: Calculate the number of moles of water using its molar mass (approximately 18.02 g/mol) and the given mass of water (200.0 g).
Step 4: Determine the mole fraction of water in the solution using the formula: \( \text{mole fraction of water} = \frac{\text{moles of water}}{\text{moles of water} + \text{moles of lactose}} \).
Step 5: Use Raoult's Law to calculate the vapor pressure of water above the solution: \( P_{\text{solution}} = \chi_{\text{water}} \times P^0_{\text{water}} \), where \( P^0_{\text{water}} \) is the vapor pressure of pure water at 338 K.
Related Practice
Textbook Question

You make a solution of a nonvolatile solute with a liquid solvent. Indicate if each of the following statements is true or false. (d) The boiling point of the solution increases in proportion to the concentration of the solute.

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Open Question
Consider two solutions, one formed by adding 10 g of glucose (C6H12O6) to 1 L of water and the other formed by adding 10 g of sucrose (C12H22O11) to 1 L of water. Calculate the vapor pressure for each solution at 20 °C; the vapor pressure of pure water at this temperature is 17.5 torr.
Textbook Question
The vapor pressure of pure water at 60 °C is 149 torr. The vapor pressure of water over a solution at 60 °C containing equal numbers of moles of water and ethylene glycol (a nonvolatile solute) is 67 torr. Is the solution ideal according to Raoult's law?
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Open Question
(b) Calculate the mass of ethylene glycol (C2H6O2) that must be added to 1.00 kg of ethanol (C2H5OH) to reduce its vapor pressure by 10.0 torr at 35 °C. The vapor pressure of pure ethanol at 35 °C is 1.00 x 10^2 torr.
Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (a) What is the mole fraction of ethanol in the solution?

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Textbook Question

At 63.5 °C, the vapor pressure of H2O is 175 torr, and that of ethanol (C2H5OH) is 400 torr. A solution is made by mixing equal masses of H2O and C2H5OH. (b) Assuming ideal solution behavior, what is the vapor pressure of the solution at 63.5 °C?

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