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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 124a

The karat scale used to describe gold alloys is based on mass percentages. (a) If an alloy is formed that is 50 mol% silver and 50 mol% gold, what is the karat number of the alloy? Use Figure 12.18 to estimate the color of this alloy.
A triangular diagram showing mass percentages of gold, silver, and copper alloys with color indicators.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Karat Scale

The karat scale is a measure of the purity of gold alloys, where 24 karats represents pure gold. The karat number indicates the mass percentage of gold in the alloy; for example, 18-karat gold contains 75% gold and 25% other metals. Understanding this scale is essential for determining the quality and value of gold jewelry.
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Mole Percent vs. Mass Percent

Mole percent refers to the ratio of the number of moles of a component to the total number of moles in a mixture, while mass percent is the mass of a component divided by the total mass of the mixture. In the context of the question, converting from mole percent to mass percent is necessary to accurately determine the karat number of the alloy.
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Mass Percent Calculation

Alloy Color and Composition

The color of a metal alloy is influenced by its composition, particularly the types and amounts of metals present. The triangular diagram provided illustrates how varying proportions of gold, silver, and copper affect the alloy's color. This relationship is crucial for predicting the visual appearance of the alloy based on its composition.
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Related Practice
Textbook Question

In their study of X-ray diffraction, William and Lawrence Bragg determined that the relationship among the wavelength of the radiation 1l2, the angle at which the radiation is diffracted 1u2, and the distance between planes of atoms in the crystal that cause the diffraction (d) is given by nl = 2d sin u. X rays from a copper X-ray tube that have a wavelength of 1.54 Å are diffracted at an angle of 14.22 degrees by crystalline silicon. Using the Bragg equation, calculate the distance between the planes of atoms responsible for diffraction in this crystal, assuming n = 1 (first-order diffraction).

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Textbook Question

Germanium has the same structure as silicon, but the unit cell size is different because Ge and Si atoms are not the same size. If you were to repeat the experiment described in the previous problem but replace the Si crystal with a Ge crystal, would you expect the X rays to be diffracted at a larger or smaller angle u?

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Textbook Question

(a) The density of diamond is 3.5 g>cm3, and that of graphite is 2.3 g>cm3. Based on the structure of buckminsterfullerene, what would you expect its density to be relative to these other forms of carbon?

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Textbook Question

The karat scale used to describe gold alloys is based on mass percentages. (b) If an alloy is formed that is 50 mol% copper and 50 mol% gold, what is the karat number of the alloy? What is the color of this alloy?

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Textbook Question

(a) What are the C¬C¬C bond angles in diamond?

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Textbook Question

(c) What atomic orbitals are involved in the stacking of graphite sheets with each other?

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