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Ch.12 - Solids and Modern Materials

Chapter 12, Problem 120

In their study of X-ray diffraction, William and Lawrence Bragg determined that the relationship among the wavelength of the radiation 1l2, the angle at which the radiation is diffracted 1u2, and the distance between planes of atoms in the crystal that cause the diffraction (d) is given by nl = 2d sin u. X rays from a copper X-ray tube that have a wavelength of 1.54 Å are diffracted at an angle of 14.22 degrees by crystalline silicon. Using the Bragg equation, calculate the distance between the planes of atoms responsible for diffraction in this crystal, assuming n = 1 (first-order diffraction).

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Hi everyone. So in this question have an X ray diffraction analysis and it's found that the X ray from sodium chloride radiation source has a wavelength of 94 PICO meters. And the selected crystalline plane distracted the radiation at an angle of 25.9°. And assuming that this is second order diffraction, which means that n equals two. We need to use the black equation and calculate the spacing between the adjacent crystal planes. We call that the bag equation. It's in times a wavelength evil to to that was the distance between the latest planes. Times sine of data. And that is an incident angle. So now if you rearrange this is sulfur. D. You get deep end times the weight blend About about two times sine of data for our values for D. This is what we're looking for for N. This is too with data We have 194 PICO meters. For an angle There's 25.9°. Send off you plug in the values for D. We're gonna get to 194 km. Bye bye to I'm signed of 25.9°. They get 444 pickle meters. Thanks for watching my video and I hope it was helpful
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Silicon carbide, SiC, has the three-dimensional structure shown in the figure.

(b) Would you expect the bonding in SiC to be predominantly ionic, metallic, or covalent?

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Textbook Question

Energy bands are considered continuous due to the large number of closely spaced energy levels. The range of energy levels in a crystal of copper is approximately 1 * 10–19 J. Assuming equal spacing between levels, the spacing between energy levels may be approximated by dividing the range of energies by the number of atoms in the crystal. (b) Determine the average spacing in J between energy levels in the copper metal in part (a).

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Textbook Question

Sodium oxide (Na2O) adopts a cubic structure with Na atoms represented by green spheres and O atoms by red spheres.

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Textbook Question

Germanium has the same structure as silicon, but the unit cell size is different because Ge and Si atoms are not the same size. If you were to repeat the experiment described in the previous problem but replace the Si crystal with a Ge crystal, would you expect the X rays to be diffracted at a larger or smaller angle u?

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Textbook Question

(a) The density of diamond is 3.5 g>cm3, and that of graphite is 2.3 g>cm3. Based on the structure of buckminsterfullerene, what would you expect its density to be relative to these other forms of carbon?

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Textbook Question

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