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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 122a

(a) The density of diamond is 3.5 g>cm3, and that of graphite is 2.3 g>cm3. Based on the structure of buckminsterfullerene, what would you expect its density to be relative to these other forms of carbon?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Density

Density is defined as mass per unit volume, typically expressed in grams per cubic centimeter (g/cm³). It is a physical property that can help distinguish between different materials. In the context of carbon allotropes, density can provide insights into their structural arrangement and bonding, influencing how tightly the atoms are packed.
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Allotropes of Carbon

Carbon exhibits several allotropes, including diamond, graphite, and buckminsterfullerene, each with distinct structural properties. Diamond has a tetrahedral lattice structure, leading to high density, while graphite has a layered structure that allows for lower density. Buckminsterfullerene, with its spherical structure, is expected to have a density that falls between those of diamond and graphite due to its unique arrangement of carbon atoms.
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Molecular Structure and Density Relationship

The molecular structure of a substance significantly influences its density. In carbon allotropes, the arrangement of carbon atoms and the type of bonding (covalent in diamond, van der Waals in graphite) determine how closely packed the atoms are. Buckminsterfullerene's spherical structure suggests a lower density than diamond but potentially higher than graphite, as its unique geometry allows for a different packing efficiency.
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Related Practice
Textbook Question

Sodium oxide (Na2O) adopts a cubic structure with Na atoms represented by green spheres and O atoms by red spheres.

(c) The unit cell edge length is 5.550 Å. Determine the density of Na2O.

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Textbook Question

In their study of X-ray diffraction, William and Lawrence Bragg determined that the relationship among the wavelength of the radiation 1l2, the angle at which the radiation is diffracted 1u2, and the distance between planes of atoms in the crystal that cause the diffraction (d) is given by nl = 2d sin u. X rays from a copper X-ray tube that have a wavelength of 1.54 Å are diffracted at an angle of 14.22 degrees by crystalline silicon. Using the Bragg equation, calculate the distance between the planes of atoms responsible for diffraction in this crystal, assuming n = 1 (first-order diffraction).

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Textbook Question

Germanium has the same structure as silicon, but the unit cell size is different because Ge and Si atoms are not the same size. If you were to repeat the experiment described in the previous problem but replace the Si crystal with a Ge crystal, would you expect the X rays to be diffracted at a larger or smaller angle u?

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Textbook Question

The karat scale used to describe gold alloys is based on mass percentages. (a) If an alloy is formed that is 50 mol% silver and 50 mol% gold, what is the karat number of the alloy? Use Figure 12.18 to estimate the color of this alloy.

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Textbook Question

The karat scale used to describe gold alloys is based on mass percentages. (b) If an alloy is formed that is 50 mol% copper and 50 mol% gold, what is the karat number of the alloy? What is the color of this alloy?

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Textbook Question

(a) What are the C¬C¬C bond angles in diamond?

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