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Ch.12 - Solids and Modern Materials
Chapter 12, Problem 68

Classify each of the following statements as true or false: (a) For molecular solids, the melting point generally increases as the strengths of the covalent bonds increase. (b) For molecular solids, the melting point generally increases as the strengths of the intermolecular forces increase.

Verified step by step guidance
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Step 1: Understand the difference between covalent bonds and intermolecular forces. Covalent bonds are the strong bonds that hold atoms together within a molecule, while intermolecular forces are weaker forces that occur between molecules.
Step 2: Analyze statement (a). In molecular solids, the molecules are held together by intermolecular forces, not covalent bonds. Therefore, the melting point is not directly related to the strength of covalent bonds within the molecules.
Step 3: Determine the truth of statement (a). Since the melting point of molecular solids is not dependent on the strength of covalent bonds, statement (a) is false.
Step 4: Analyze statement (b). The melting point of molecular solids is influenced by the strength of intermolecular forces. Stronger intermolecular forces require more energy to overcome, leading to a higher melting point.
Step 5: Determine the truth of statement (b). Since the melting point generally increases with stronger intermolecular forces, statement (b) is true.
Related Practice
Textbook Question

The coordination number for the Al3+ ion is typically between four and six. Use the anion coordination number to determine the Al3 + coordination number in the following compounds: (b) Al2O3 where the oxygen ions are six coordinate.

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Textbook Question

The coordination number for the Al3+ ion is typically between four and six. Use the anion coordination number to determine the Al3 + coordination number in the following compounds: (c) AlN where the nitride ions are four coordinate.

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Open Question
Classify each of the following statements as true or false: (a) Although both molecular solids and covalent-network solids have covalent bonds, the melting points of molecular solids are much lower because their covalent bonds are much weaker. (b) Other factors being equal, highly symmetric molecules tend to form solids with higher melting points than asymmetrically shaped molecules.
Textbook Question

Both covalent-network solids and ionic solids can have melting points well in excess of room temperature, and both can be poor conductors of electricity in their pure form. However, in other ways their properties are quite different. (a) Which type of solid is more likely to dissolve in water?

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Textbook Question

For each of the following pairs of semiconductors, which one will have the larger band gap: (a) CdS or CdTe?

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Textbook Question
The smectic liquid crystalline phase can be said to be more highly ordered than the nematic phase. In what sense is this true?
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