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Ch.11 - Liquids and Intermolecular Forces
Chapter 11, Problem 56c

Appendix B lists the vapor pressure of water at various external pressures. (c) A city at an altitude of 5000 ft above sea level has a barometric pressure of 633 torr. To what temperature would you have to heat water to boil it in this city?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Vapor Pressure

Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid form at a given temperature. It indicates how readily a substance will evaporate; higher vapor pressure means a substance will boil at a lower temperature. Understanding vapor pressure is crucial for determining boiling points under varying external pressures.
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Boiling Point

The boiling point of a liquid is the temperature at which its vapor pressure equals the external pressure surrounding the liquid. At higher altitudes, the atmospheric pressure is lower, which decreases the boiling point of water. This concept is essential for calculating the temperature needed to boil water in locations with different barometric pressures.
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Barometric Pressure

Barometric pressure, or atmospheric pressure, is the pressure exerted by the weight of the atmosphere above a given point. It varies with altitude; as altitude increases, barometric pressure decreases. This relationship is important for understanding how boiling points change in different geographical locations, such as cities at high elevations.
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Related Practice
Textbook Question

(a)Two pans of water are on different burners of a stove.One pan of water is boiling vigorously, while the other is boiling gently. What can be said about the temperature of the water in the two pans?

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Textbook Question

You are high up in the mountains and boil water to make some tea. However, when you drink your tea, it is not as hot as it should be. You try again and again, but the water is just not hot enough to make a hot cup of tea. Which is the best explanation for this result? (a) High in the mountains, it is probably very dry, and so the water is rapidly evaporating from your cup and cooling it. (b) High in the mountains, it is probably very windy, and so the water is rapidly evaporating from your cup and cooling it. (c) High in the mountains, the air pressure is significantly less than 1 atm, so the boiling point of water is much lower than at sea level. (d) High in the mountains, the air pressure is significantly less than 1 atm, so the boiling point of water is much higher than at sea level.

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Textbook Question

Using the vapor-pressure curves in Figure 11.25, (d) estimate the external pressure at which diethyl ether will boil at 40 °C.

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Textbook Question
(b) Could you measure the triple point of water by measuring the temperature in a vessel in which water vapor, liquid water, and ice are in equilibrium under 1 atm of air? Explain.
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Textbook Question

Referring to Figure 11.29, describe the phase changes (and the temperatures at which they occur) when CO2 is heated from -80 to -20°C at (a) a constant pressure of 3 atm,

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Textbook Question

The phase diagram for neon is

Use the phase diagram to answer the following questions. (a) What is the approximate value of the normal melting point?

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