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Ch.11 - Liquids and Intermolecular Forces

Chapter 11, Problem 54

You are high up in the mountains and boil water to make some tea. However, when you drink your tea, it is not as hot as it should be. You try again and again, but the water is just not hot enough to make a hot cup of tea. Which is the best explanation for this result? (a) High in the mountains, it is probably very dry, and so the water is rapidly evaporating from your cup and cooling it. (b) High in the mountains, it is probably very windy, and so the water is rapidly evaporating from your cup and cooling it. (c) High in the mountains, the air pressure is significantly less than 1 atm, so the boiling point of water is much lower than at sea level. (d) High in the mountains, the air pressure is significantly less than 1 atm, so the boiling point of water is much higher than at sea level.

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Hello. Everyone in this video. We're giving a scenario and then we're trying to see which situation would fit best. So the scenario is that you're camping at the top of a mountain and you're trying to boil a pot of water. So we're seeing at one temperature the boil, the water will boil. And we're trying to see what the pressure of the air is. So let's think about this. Since we're at the top of a mountain, it means we're at a higher altitude. If we're at a higher altitude we're going to have low pressure or lower pressure. When we mean lower pressure, we mean less than one A. T. M. And if we have lower pressure than the bp of water, so the boiling point of water is also going to be lower. If we follow this little road map here then are correct answer should be B is that the water will boil at a lower temperature and that our air pressure is going to be less than 1 80 M. So our final answer for this problem is going to be beep. Thank you all so much for watching
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The critical temperatures and pressures of a series of halogenated methanes are as follows: (c) Predict the critical temperature and pressure for CCl4 based on the trends in this table. Look up the experimentally determined critical temperatures and pressures for CCl4, using a source such as the CRC Handbook of Chemistry and Physics, and suggest a reason for any discrepancies.

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(a) Place the following substances in order of increasing volatility: CH4, CBr4, CH2Cl2, CH3Cl, CHBr3, and CH2Br2. (b) How do the boiling points vary through this series? (c) Explain your answer to part (b) in terms of intermolecular forces.

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Using the vapor-pressure curves in Figure 11.25, (d) estimate the external pressure at which diethyl ether will boil at 40 °C.

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Textbook Question
(b) Could you measure the triple point of water by measuring the temperature in a vessel in which water vapor, liquid water, and ice are in equilibrium under 1 atm of air? Explain.
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