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Ch 18: A Macroscopic Description of Matter
Chapter 18, Problem 18

A 24-cm-diameter vertical cylinder is sealed at the top by a frictionless 20 kg piston. The piston is 84 cm above the bottom when the gas temperature is 303°C. The air above the piston is at 1.00 atm pressure. b. What will the height of the piston be if the temperature is lowered to 15°C?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law relates the pressure, volume, temperature, and number of moles of a gas through the equation PV = nRT. In this scenario, it helps us understand how changes in temperature affect the volume of gas when pressure is constant, allowing us to predict the new height of the piston.
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Charles's Law

Charles's Law states that the volume of a gas is directly proportional to its temperature (in Kelvin) when pressure is held constant. This principle is crucial for solving the problem, as it allows us to determine how the height of the piston changes with the decrease in temperature from 303°C to 15°C.
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Pressure-Volume Relationship

In a closed system, the pressure exerted by a gas is related to its volume and temperature. When the temperature decreases, the gas molecules lose energy, leading to a decrease in pressure if the volume is allowed to change. Understanding this relationship is essential for calculating the new height of the piston as the gas cools.
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