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Ch.14 - Solutions
Chapter 14, Problem 106

Water softeners often replace calcium ions in hard water with sodium ions. Since sodium compounds are soluble, the presence of sodium ions in water does not cause the white, scaly residues caused by calcium ions. However, calcium is more beneficial to human health than sodium because calcium is a necessary part of the human diet, while high levels of sodium intake are linked to increases in blood pressure. The U.S. Food and Drug Administration (FDA) recommends that adults ingest less than 2.4 g of sodium per day. How many liters of softened water, containing a sodium concentration of 0.050% sodium by mass, would a person have to consume to exceed the FDA recommendation? (Assume a water density of 1.0 g/mL.)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hard Water and Water Softeners

Hard water contains high concentrations of calcium and magnesium ions, which can lead to scale buildup in pipes and appliances. Water softeners work by exchanging these hard ions for sodium ions, which do not precipitate out and cause scaling. This process improves the quality of water for household use but alters its mineral content, impacting dietary intake.
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Sodium Concentration and Mass Percent

Sodium concentration in a solution can be expressed as mass percent, which indicates the mass of sodium per 100 grams of solution. In this case, a 0.050% sodium by mass means that there are 0.050 grams of sodium in every 100 grams of softened water. Understanding this concept is crucial for calculating the total sodium intake from the volume of water consumed.
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Daily Sodium Intake Recommendations

The FDA recommends that adults limit their sodium intake to less than 2.4 grams per day to reduce the risk of hypertension and other health issues. This guideline is essential for evaluating how much softened water a person can safely consume without exceeding the recommended sodium limit, thereby ensuring a balance between hydration and health.
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Related Practice
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A saturated solution forms when 0.0537 L of argon, at a pressure of 1.0 atm and temperature of 25 °C, is dissolved in 1.0 L of water. Calculate the Henry's law constant for argon.

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Textbook Question

A gas has a Henry's law constant of 0.112 M>atm. What total volume of solution is needed to completely dissolve 1.65 L of the gas at a pressure of 725 torr and a temperature of 25 °C?

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The Safe Drinking Water Act (SDWA) sets a limit for mercury—a toxin to the central nervous system—at 0.0020 ppm by mass. Water suppliers must periodically test their water to ensure that mercury levels do not exceed this limit. Suppose water becomes contaminated with mercury at twice the legal limit (0.0040 ppm). How much of this water would a person have to consume to ingest 50.0 mg of mercury?

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Textbook Question

An isotonic solution contains 0.90% NaCl mass to volume. Calculate the percent mass to volume for isotonic solutions containing each solute at 25 °C. Assume a van't Hoff factor of 1.9 for all ionic solutes. a. KCl

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Textbook Question

Magnesium citrate, Mg3(C6H5O7)2, belongs to a class of laxatives called hyperosmotics, which cause rapid emptying of the bowel. When a concentrated solution of magnesium citrate is consumed, it passes through the intestines, drawing water and promoting diarrhea, usually within 6 hours. Calculate the osmotic pressure of a magnesium citrate laxative solution containing 28.5 g of magnesium citrate in 235 mL of solution at 37 °C (approximate body temperature). Assume complete dissociation of the ionic compound.

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Textbook Question

When HNO2 is dissolved in water, it partially dissociates according to the equation HNO2 ⇌ H+ + NO2-. A solution is prepared that contains 7.050 g of HNO2 in 1.000 kg of water. Its freezing point is -0.2929 °C. Calculate the fraction of HNO2 that has dissociated.

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