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Ch.17 - Aqueous Ionic Equilibrium
Chapter 17, Problem 54e

Determine whether or not the mixing of each pair of solutions results in a buffer. e. 105.0 mL of 0.15 M CH3NH2; 95.0 mL of 0.10 M HCl

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Identify the components involved in the solution: CH₃NH₂ is a weak base and HCl is a strong acid.
Calculate the moles of CH₃NH₂ using the formula: moles = concentration (M) × volume (L).
Calculate the moles of HCl using the formula: moles = concentration (M) × volume (L).
Determine if the moles of HCl are less than, equal to, or greater than the moles of CH₃NH₂ to see if there is an excess of weak base or if the strong acid completely neutralizes the weak base.
Conclude whether a buffer is formed: A buffer is formed if there is a significant amount of weak base and its conjugate acid (formed from the reaction with the strong acid) present in the solution.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Buffer Solutions

A buffer solution is a system that resists changes in pH upon the addition of small amounts of acid or base. It typically consists of a weak acid and its conjugate base or a weak base and its conjugate acid. Buffers are crucial in maintaining stable pH levels in various chemical and biological processes.
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Buffer Solutions

Weak Bases and Their Conjugate Acids

In this scenario, CH3NH2 (methylamine) is a weak base, and when it reacts with HCl (a strong acid), it forms its conjugate acid, CH3NH3+. The presence of both the weak base and its conjugate acid is essential for the formation of a buffer solution, allowing the system to neutralize added acids or bases.
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Conjugate Acid-Base Relationships

Stoichiometry of Acid-Base Reactions

Stoichiometry involves the calculation of reactants and products in chemical reactions. In this case, determining whether a buffer forms requires calculating the moles of CH3NH2 and HCl to see if they can coexist in a ratio that maintains the buffer capacity. Understanding the stoichiometric relationships helps predict the outcome of mixing these solutions.
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Acid-Base Reaction