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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Chapter 10, Problem 58

Write orbital diagrams (boxes with arrows in them) to represent the electron configurations of carbon before and after sp hybridization.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. For carbon, which has six electrons, the ground state configuration is 1s² 2s² 2p². This notation indicates that two electrons occupy the 1s orbital, two occupy the 2s orbital, and two occupy the 2p orbitals, which is essential for understanding how electrons are arranged before hybridization.
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Electron Configuration Example

Hybridization

Hybridization is the process by which atomic orbitals mix to form new hybrid orbitals, which can accommodate bonding. In the case of carbon, sp hybridization occurs when one s orbital and one p orbital combine to form two equivalent sp hybrid orbitals. This allows carbon to form four equivalent bonds, as seen in molecules like methane (CH₄), enhancing its bonding capabilities.
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Orbital Diagrams

Orbital diagrams visually represent the arrangement of electrons in an atom's orbitals using boxes and arrows. Each box represents an orbital, and arrows indicate the presence of electrons, with their direction denoting spin. These diagrams are crucial for illustrating the electron configurations of carbon before and after hybridization, helping to visualize how the electron distribution changes.
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Related Practice
Open Question
Write orbital diagrams (boxes with arrows in them) to represent the electron configurations—without hybridization—for all the atoms in PH₃. Circle the electrons involved in bonding. Draw a three-dimensional sketch of the molecule and show orbital overlap. What bond angle do you expect from the unhybridized orbitals? How well does valence bond theory agree with the experimentally measured bond angle of 93.3°?
Textbook Question

Write orbital diagrams (boxes with arrows in them) to represent the electron configurations—without hybridization—for all the atoms in SF2. Circle the electrons involved in bonding. Draw a three-dimensional sketch of the molecule and show orbital overlap. What bond angle do you expect from the unhybridized orbitals? How well does valence bond theory agree with the experimentally measured bond angle of 98.2° ?

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Textbook Question

Write orbital diagrams (boxes with arrows in them) to represent the electron configuration of carbon before and after sp3 hybridization.

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Textbook Question

Which hybridization scheme allows the formation of at least one p bond? sp3, sp2, sp3d2

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Textbook Question

Which hybridization scheme allows the central atom to form more than four bonds? sp3, sp3d, sp2

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Textbook Question

Write a hybridization and bonding scheme for each molecule. Sketch the molecule, including overlapping orbitals, and label all bonds using the notation shown in Examples 10.6 and 10.7. a. CCl4

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