The valence electron configurations of several atoms are shown here. How many bonds can each atom make without hybridization? c. O 2s22p4
Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
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Ch.10 - Chemical Bonding II: Molecular Shapes & Valence Bond Theory
Problem 57
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Chapter 10, Problem 57
Write orbital diagrams (boxes with arrows in them) to represent the electron configuration of carbon before and after sp3 hybridization.
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Start by writing the ground state electron configuration of carbon, which is 1s^2 2s^2 2p^2.
Draw the orbital diagram for the ground state configuration: two arrows in the 1s box, two arrows in the 2s box, and two arrows in the 2p boxes, with one arrow in each of the first two 2p boxes.
Understand that in sp3 hybridization, one electron from the 2s orbital is promoted to the empty 2p orbital, resulting in the configuration 1s^2 2s^1 2p^3.
Draw the orbital diagram for the hybridized state: two arrows in the 1s box, one arrow in the 2s box, and one arrow in each of the three 2p boxes.
Combine the 2s and 2p orbitals to form four equivalent sp3 hybrid orbitals, each containing one electron, ready to form covalent bonds.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Electron Configuration
Electron configuration describes the distribution of electrons in an atom's orbitals. For carbon, which has six electrons, the ground state configuration is 1s² 2s² 2p². This notation indicates that two electrons occupy the 1s orbital, two occupy the 2s orbital, and two occupy the 2p orbitals, which is crucial for understanding how carbon bonds and hybridizes.
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Electron Configuration Example
Orbital Diagrams
Orbital diagrams visually represent the arrangement of electrons in an atom's orbitals using boxes and arrows. Each box represents an orbital, and arrows indicate the presence of electrons, with their direction showing spin. These diagrams help illustrate the filling order of orbitals according to the Aufbau principle, Hund's rule, and the Pauli exclusion principle, which are essential for understanding electron configurations.
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sp3 Hybridization
sp3 hybridization occurs when one s orbital and three p orbitals mix to form four equivalent hybrid orbitals, which are oriented tetrahedrally. In carbon, this hybridization allows for the formation of four sigma bonds, as seen in molecules like methane (CH₄). Understanding sp3 hybridization is key to grasping how carbon can form stable covalent bonds with other atoms.
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Hybridization
Related Practice
Textbook Question
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Open Question
Write orbital diagrams (boxes with arrows in them) to represent the electron configurations—without hybridization—for all the atoms in PH₃. Circle the electrons involved in bonding. Draw a three-dimensional sketch of the molecule and show orbital overlap. What bond angle do you expect from the unhybridized orbitals? How well does valence bond theory agree with the experimentally measured bond angle of 93.3°?
Textbook Question
Write orbital diagrams (boxes with arrows in them) to represent the electron configurations—without hybridization—for all the atoms in SF2. Circle the electrons involved in bonding. Draw a three-dimensional sketch of the molecule and show orbital overlap. What bond angle do you expect from the unhybridized orbitals? How well does valence bond theory agree with the experimentally measured bond angle of 98.2° ?
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Textbook Question
Write orbital diagrams (boxes with arrows in them) to represent the electron configurations of carbon before and after sp hybridization.
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Textbook Question
Which hybridization scheme allows the formation of at least one p bond? sp3, sp2, sp3d2
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Textbook Question
Which hybridization scheme allows the central atom to form more than four bonds? sp3, sp3d, sp2
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