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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 152

Assume that you dissolve 10.0 g of a mixture of NaOH and Ba(OH)2 in 250.0 mL of water and titrate with 1.50 M hydrochloric acid. The titration is complete after 108.9 mL of the acid has been added. What is the mass in grams of each substance in the mixture?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. It involves using balanced chemical equations to determine the relationships between the amounts of substances consumed and produced. In this question, stoichiometry will help relate the moles of hydrochloric acid used in the titration to the moles of NaOH and Ba(OH)2 in the mixture.
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Titration

Titration is a quantitative analytical technique used to determine the concentration of a solute in a solution. It involves the gradual addition of a titrant (in this case, hydrochloric acid) to a solution until the reaction reaches completion, indicated by a color change or a specific endpoint. Understanding the titration process is essential for calculating the amounts of NaOH and Ba(OH)2 in the mixture based on the volume and concentration of the acid used.
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Molarity and Moles

Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. To solve the problem, it is necessary to convert the volume of hydrochloric acid used in the titration into moles, which can then be used to find the moles of NaOH and Ba(OH)2. This concept is crucial for determining the mass of each component in the original mixture.
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Related Practice
Textbook Question

A 1.268 g sample of a metal carbonate (MCO3) was treated with 100.00 mL of 0.1083 M sulfuric acid (H2SO4), yielding CO2 gas and an aqueous solution of the metal sulfate (MSO4). The solution was boiled to remove all the dissolved CO2 and was then titrated with 0.1241 M NaOH. A 71.02 mL volume of NaOH was required to neutralize the excess H2SO4. (a) What is the identity of the metal M?

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Textbook Question

(b) How many liters of CO2 gas were produced if the density of CO2 is 1.799 g/L?

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Textbook Question

Element M is prepared industrially by a two-step procedure according to the following (unbalanced) equations:

Assume that 0.855 g of M2O3 is submitted to the reaction sequence. When the HCl produced in step (2) is dissolved in water and titrated with 0.511 M NaOH, 144.2 mL of the NaOH solution is required to neutralize the HCl. (a) Balance both equations.

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Textbook Question
Four solutions are prepared and mixed in the following order: (a) Start with 100.0 mL of 0.100 M BaCl2 (b) Add 50.0 mL of 0.100 M AgNO3 (c) Add 50.0 mL of 0.100 M H2SO4 (d) Add 250.0 mL of 0.100 M NH3. Write an equation for any reaction that occurs after each step, and calculate the concentrations of Ba2+, Cl-, NO3-, NH3, and NH4+ in the final solution, assuming that all reactions go to completion.
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Textbook Question

To 100.0 mL of a solution that contains 0.120 M Cr(NO3)2 and 0.500 M HNO3 is added to 20.0 mL of 0.250 M K2Cr2O7. The dichromate and chromium(II) ions react to give chromium(III) ions. (a) Write a balanced net ionic equation for the reaction.

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Textbook Question

(b) Calculate the concentrations of all ions in the solution after reaction. Check your concentrations to make sure that the solution is electrically neutral.

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