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Ch.17 - Applications of Aqueous Equilibria

Chapter 17, Problem 40a

The following pictures represent solutions that contain one or more of the compounds H2A, NaHA, and Na2A, where H2A is a weak diprotic acid. (Na+ ions and solvent water molecules have been omitted for clarity.)

(a) Which of the solutions are buffer solutions?

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hi everyone for this problem. It reads the following diagram represents four different solutions that may contain any of these four species in varying concentrations. potassium ions are not shown for clarity identify which of these solutions is a buffer. So we want to identify which is a buffer. So let's go ahead and define what a buffer is. So a buffer is a solution of a weak acid and its conjugate base. Okay, so we just have to find out which solution has that. So let's go ahead and take a look at what we have for solution a this solution only contains H2 a molecules and it's undisc created form. So this is not a buffer solution B. This solution contains H two A which is a weak acid and its conjugate base H A. Okay, so this solution is a buffer. So let's just write out what we have. So for four solution A we only had the weak acid. Okay. And it's in it's un disassociated form for solution B. We have the weak acid plus its conjugate base. Okay, so this is a buffer for solutions. See this solution only contains the conjugate base. Okay, so this is not a buffer and solution D this solution only contains the A two minus ions which is a conjugate base of H A minus and this is not a buffer. So our correct answer for this problem is going to be B. B is the diagram that shows the buffer. Okay, so that is it for this problem? I hope this was helpful
Related Practice
Textbook Question

The strong acid HA is mixed with an equal molar amount of aqueous NaOH. Which of the following pictures represents the equilibrium state of the solution? (Na+ ions and solvent water molecules have been omitted for clarity.)

(A) (B) (C) (D)

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Textbook Question
The following pictures represent initial concentrations in solutions that contain a weak acid HA (pKa = 6.0) and its sodium salt NaA. (Na+ ions and solvent water molecules have been omitted for clarity.)

. (c) Draw a picture that represents the equilibrium state of solution (1) after the addition of two OH-ions.
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Textbook Question

The following pictures represent initial concentrations in solutions that contain a weak acid HA (pKa = 6.0) and its sodium salt NaA. (Na+ ions and solvent water molecules have been omitted for clarity.)

. (b) Draw a picture that represents the equilibrium state of solution (1) after the addition of two H3O+ ions.

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Textbook Question

The following pictures represent solutions that contain one or more of the compounds H2A, NaHA, and Na2A, where H2A is a weak diprotic acid. (Na+ ions and solvent water molecules have been omitted for clarity.)

(b) Which solution has the greatest buffer capacity?

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Textbook Question

The following plot shows two pH titration curves, each representing the titration of 50.0 mL of 0.100 M acid with 0.100 M NaOH:

. (a) Which of the two curves represents the titration of a strong acid? Which represents a weak acid?

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Textbook Question

The following plot shows two pH titration curves, each representing the titration of 50.0 mL of 0.100 M acid with 0.100 M NaOH:

. (b) What is the approximate pH at the equivalence point for each of the acids?

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