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Ch.10 - Gases: Their Properties & Behavior
Chapter 10, Problem 117

The Earth's atmosphere has a mass of approximately 5.15 * 1015 kg. If the average molar mass of air is 28.8 g/mol, how many moles of gas make up the atmosphere? What is the volume of the atmosphere in liters under conditions of STP? (Note: The average molar mass of air is the weighted average of the molar mass of nitrogen and oxygen. 0.20132.0 g>mol2 + 0.80128.0 g>mol2 = 28.8 g>mol.)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is calculated by summing the atomic masses of all atoms in a molecule. In this question, the average molar mass of air is given as 28.8 g/mol, which is essential for converting the total mass of the atmosphere into moles.
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Moles and Avogadro's Number

A mole is a unit in chemistry that represents 6.022 x 10²³ entities, such as atoms or molecules. To find the number of moles in a given mass, the formula used is: moles = mass (g) / molar mass (g/mol). This concept is crucial for determining how many moles of gas are present in the Earth's atmosphere based on its total mass and the average molar mass of air.
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Standard Temperature and Pressure (STP)

Standard Temperature and Pressure (STP) refers to a set of conditions commonly used in gas calculations, defined as 0 degrees Celsius (273.15 K) and 1 atmosphere of pressure. Under STP, one mole of an ideal gas occupies 22.4 liters. This concept is necessary for calculating the volume of the atmosphere in liters once the number of moles has been determined.
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Related Practice
Textbook Question

Two 112-L tanks are filled with gas at 330 K. One contains 5.00 mol of Kr, and the other contains 5.00 mol of O2. Considering the assumptions of kinetic–molecular theory, rank the gases from low to high for each of the following properties. (d) Pressure

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Textbook Question
The reaction NO1g2 + NO21g2 ∆ N2O31g2 takes place in the atmosphere with Kc = 13 at 298 K. A gas mixture is prepared with 2.0 mol NO and 3.0 mol NO2 and an initial total pressure of 1.65 atm. (b) What is the volume of the container?
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Textbook Question
Name the regions of the atmosphere. What property is used to distinguish between different regions of the atmosphere?
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Textbook Question
The troposphere contains about three quarters of the mass of the entire atmosphere. The troposphere is only 12 km thick while the whole atmosphere is about 120 km thick. Explain why the troposphere contains such a large fraction of the total mass.
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Textbook Question
The percent by volume of oxygen (20.95%) is constant throughout the troposphere. (a) Express this percentage as a mole fraction.
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Textbook Question
A driver with a nearly empty fuel tank may say she is 'running on fumes.' If a 15.0-gallon automobile gas tank had only gasoline vapor remaining in it, what is the farthest the vehicle could travel if it gets 20.0 miles per gallon on liquid gasoline? Assume the average molar mass of molecules in gasoline is 105 g/mol, the density of liquid gasoline is 0.75 g/mL, the pressure is 743 mm Hg, and the temperature is 25 °C.
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