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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 29b

(b) If a limestone sculp- ture were treated to form a surface layer of calcium sul- fate, would this help to slow down the effects of acid rain? Explain.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid Rain

Acid rain is precipitation that has a lower pH than normal, typically due to the presence of sulfuric and nitric acids formed from atmospheric pollutants. It can cause significant damage to buildings, sculptures, and natural landscapes by reacting with minerals in the materials, leading to erosion and degradation. Understanding the chemical composition of acid rain is crucial for evaluating its effects on various substances.
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Calcium Sulfate

Calcium sulfate is a chemical compound that can form a protective layer on surfaces when applied. This layer can act as a barrier, potentially reducing the direct exposure of the underlying material to acidic components in rain. Its effectiveness in slowing down the deterioration of limestone sculptures depends on its ability to withstand acidic conditions and its adherence to the surface.
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Chemical Weathering

Chemical weathering refers to the process by which rocks and minerals undergo chemical reactions that alter their composition and structure, often due to environmental factors like acid rain. In the case of limestone, which is primarily composed of calcium carbonate, acid rain can lead to the dissolution of the rock, resulting in loss of material. Understanding this process is essential for assessing how protective treatments like calcium sulfate can mitigate damage.
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Chemical Properties
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(a) When chlorine atoms react with atmospheric ozone, what are the products of the reaction?

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(b) Based on average bond enthalpies, would you expect a photon capable of dissociating a C-Cl bond to have sufficient energy to dissociate a C-Br bond?

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Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (b) What is the maximum strength of a bond, in kJ>mol, that can be bro- ken by absorption of a photon of 335-nm light?

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Textbook Question

Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (d) Write out the formaldehyde photodis- sociation reaction, showing Lewis-dot structures.

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Textbook Question

An important reaction in the formation of photochemical smog is the photodissociation of NO : NO2 + hv → NO(g) + O(g) The maximum wavelength of light that can cause this reac- tion is 420 nm. (a) In what part of the electromagnetic spec- trum is light with this wavelength found?

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