Chapter 18, Problem 32a
An important reaction in the formation of photochemical smog is the photodissociation of NO : NO2 + hv → NO(g) + O(g) The maximum wavelength of light that can cause this reac- tion is 420 nm. (a) In what part of the electromagnetic spec- trum is light with this wavelength found?
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(b) If a limestone sculp- ture were treated to form a surface layer of calcium sul- fate, would this help to slow down the effects of acid rain? Explain.
Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (b) What is the maximum strength of a bond, in kJ>mol, that can be bro- ken by absorption of a photon of 335-nm light?
Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (d) Write out the formaldehyde photodis- sociation reaction, showing Lewis-dot structures.
What is the molarity of Na+ in a solution of NaCl whose salinity is 5.6 if the solution has a density of 1.03 g>mL?
Phosphorus is present in seawater to the extent of 0.07 ppm by mass. Assuming that the phosphorus is present as dihydrogenphosphate, H2PO4-, calculate the correspond-ing molar concentration of H2PO4- in seawater.
The enthalpy of evaporation of water is 40.67 kJ/mol. Sunlight striking Earth's surface supplies 168 W per square meter (1 W = 1 watt = 1 J/s). (a) Assuming that evaporation of water is due only to energy input from the Sun, calculate how many grams of water could be evaporated from a 1.00 square meter patch of ocean over a 12-h day