Chapter 18, Problem 64
Show how Equations 18.7 and 18.9 can be added to give Equation 18.10.
Video transcript
A reaction for converting ketones to lactones, called the Baeyer–Villiger reaction,
is used in the manufacture of plastics and pharmaceu- ticals. 3-Chloroperbenzoic acid is shock-sensitive, how- ever, and prone to explode. Also, 3-chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide?
In the following three instances, which choice is greener in a chemical process? Explain. (a) A reaction that can be run at 350 K for 12 h without a catalyst or one that can be run at 300 K for 1 h with a reusable catalyst.
Suppose that on another planet the atmosphere consists of 17% Kr, 38% CH4, and 45% O2. What is the average molar mass at the surface? What is the average molar mass at an altitude at which all the O2 is photodissociated?
(a) What is the difference between a CFC and an HFC?
Natural gas consists primarily of methane, CH4(g). (b) Write a balanced chemical equation for the incomplete combustion of methane to product CO(g) as the only carbon-containg product.
One of the possible consequences of climate change is an increase in the temperature of ocean water. The oceans serve as a 'sink' for CO2 by dissolving large amounts of it.
(a) The figure below shows the solubility of CO2 in water as a function of temperature. Does CO2 behave more or less similarly to other gases in this respect?