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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 60

In the following three instances, which choice is greener in a chemical process? Explain. (a) A reaction that can be run at 350 K for 12 h without a catalyst or one that can be run at 300 K for 1 h with a reusable catalyst.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Green Chemistry Principles

Green chemistry focuses on designing chemical processes that minimize waste and reduce the use of hazardous substances. It emphasizes sustainability and efficiency, aiming to create products and processes that are environmentally friendly. Understanding these principles helps evaluate the environmental impact of different chemical reactions.
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Catalysis

Catalysis involves the use of a substance (catalyst) that increases the rate of a chemical reaction without being consumed in the process. Catalysts can significantly lower the energy required for reactions, allowing them to occur under milder conditions. The use of reusable catalysts is particularly important in green chemistry as it reduces waste and resource consumption.
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Temperature and Reaction Time

The temperature at which a reaction occurs can influence its rate and the energy required for the reaction. Generally, higher temperatures can increase reaction rates but may also lead to greater energy consumption and potential side reactions. Evaluating the trade-off between temperature and reaction time is crucial for determining the overall efficiency and environmental impact of a chemical process.
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Related Practice
Textbook Question

In the lime soda process once used in large scale munici-pal water softening, calcium hydroxide prepared from lime and sodium carbonate are added to precipitate Ca2+ as CaCO3(s) and Mg2+ as Mg(OH)2(s): Ca2+(aq) + CO32-(aq) → CaCO3(s) Mg2+(aq) + 2 OH-(aq) → MgOH2(aq) How many moles of Ca(OH)2 and Na2CO3 should be added to soften (remove the Ca2+ and Mg2+) 1200 L of water in which [Ca2+] = 5.0x10-4 M and [Mg2+] = 7.0x10-4 M?

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Textbook Question

(b) Draw the Lewis structures of two example THMs.

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Textbook Question

A reaction for converting ketones to lactones, called the Baeyer–Villiger reaction,

is used in the manufacture of plastics and pharmaceu- ticals. 3-Chloroperbenzoic acid is shock-sensitive, how- ever, and prone to explode. Also, 3-chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide?

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Textbook Question

Suppose that on another planet the atmosphere consists of 17% Kr, 38% CH4, and 45% O2. What is the average molar mass at the surface? What is the average molar mass at an altitude at which all the O2 is photodissociated?

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Textbook Question

Show how Equations 18.7 and 18.9 can be added to give Equation 18.10.

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Textbook Question

(a) What is the difference between a CFC and an HFC?

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