Chapter 9, Problem 28a2
The figure that follows contains ball-and-stick drawings of three possible shapes of an AF4 molecule. (a) For each shape, give the electron-domain geometry on which the molecular geometry is based. ii.
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For each of these contour representations of molecular orbitals, identify (a) the atomic orbitals (s or p) used to construct the MO (iii)
For each of these contour representations of molecular orbitals, identify (b) the type of MO (s or p) (iii)
Consider the Lewis structure for acetic acid, which is known as vinegar: (b) What are the hybridizations of the orbitals on the two oxygen atoms, and what are the approximate bond angles at the oxygen that is connected to carbon and hydrogen? What are the hybridizations of the orbitals on the two oxygen atoms?
For each of these contour representations of molecular orbitals, identify (b) the type of MO (s or p) (i)
For each molecule (a)–(f), indicate how many different electron-domain geometries are consistent with the molecular geometry shown. a.
The molecule shown here is difluoromethane 1CH2F22, which is used as a refrigerant called R-32. (c) If the molecule is polar, which of the following describes the direction of the overall dipole moment vector in the molecule: (i) from the carbon atom toward a fluorine atom, (ii) from the carbon atom to a point midway between the fluorine atoms, (iii) from the carbon atom to a point midway between the hydrogen atoms, or (iv) from the carbon atom toward a hydrogen atom?