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Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 11b1

For each of these contour representations of molecular orbitals, identify (b) the type of MO (s or p) (i)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molecular Orbitals (MOs)

Molecular orbitals are formed by the combination of atomic orbitals when atoms bond together. They can be classified as bonding, antibonding, or non-bonding, depending on the phase relationship of the combining atomic orbitals. Understanding MOs is crucial for predicting the electronic structure and properties of molecules.
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Types of Atomic Orbitals

Atomic orbitals are regions in an atom where there is a high probability of finding electrons. The main types are s, p, d, and f orbitals, each with distinct shapes and energy levels. S orbitals are spherical, while p orbitals are dumbbell-shaped, which influences how they combine to form molecular orbitals.
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Contour Representations

Contour representations are graphical depictions of molecular orbitals that illustrate the regions of space where electrons are likely to be found. These representations help visualize the shape and orientation of the orbitals, making it easier to identify whether they are s or p type based on their geometry.
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Related Practice
Textbook Question

For each of these contour representations of molecular orbitals, identify (b) the type of MO (s or p) (iii)

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Textbook Question

Consider the Lewis structure for acetic acid, which is known as vinegar: (b) What are the hybridizations of the orbitals on the two oxygen atoms, and what are the approximate bond angles at the oxygen that is connected to carbon and hydrogen? What are the hybridizations of the orbitals on the two oxygen atoms?

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Textbook Question

The figure that follows contains ball-and-stick drawings of three possible shapes of an AF4 molecule. (a) For each shape, give the electron-domain geometry on which the molecular geometry is based. ii.

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Textbook Question

For each molecule (a)–(f), indicate how many different electron-domain geometries are consistent with the molecular geometry shown. a.

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Textbook Question

The molecule shown here is difluoromethane 1CH2F22, which is used as a refrigerant called R-32. (c) If the molecule is polar, which of the following describes the direction of the overall dipole moment vector in the molecule: (i) from the carbon atom toward a fluorine atom, (ii) from the carbon atom to a point midway between the fluorine atoms, (iii) from the carbon atom to a point midway between the hydrogen atoms, or (iv) from the carbon atom toward a hydrogen atom?

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Textbook Question

The following plot shows the potential energy of two Cl atoms as a function of the distance between them. (c) If the Cl2 molecule is compressed under higher and higher pressure, does the Cl–Cl bond become stronger or weaker?

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