Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 86
The following observations are made about two hypothetical elements A and B: The A¬A and B¬B bond lengths in the elemental forms of A and B are 236 and 194 pm, respectively. A and B react to form the binary compound AB2, which has a linear structure (that is B-A-B = 180°). Based on these statements, predict the separation between the two B nuclei in a molecule of AB2.
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Textbook Question
In Table 7.8, the bonding atomic radius of neon is listed as
58 pm, whereas that for xenon is listed as 140 pm. A classmate
of yours states that the value for Xe is more realistic
than the one for Ne. Is she correct? If so, what is the basis
for her statement?
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Textbook Question
The As ¬ As bond length in elemental arsenic is 2.48 Å. The Cl ¬ Cl bond length in Cl2 is 1.99 Å. (a) Based on these data, what is the predicted As ¬ Cl bond length in arsenic trichlo- ride, AsCl3, in which each of the three Cl atoms is bonded to the As atom?
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Textbook Question
The As ¬ As bond length in elemental arsenic is 2.48 Å. The Cl ¬ Cl bond length in Cl2 is 1.99 Å. (b) What bond length is predicted for AsCl3, using the atomic radii in Figure 7.7?
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Textbook Question
Elements in group 7A in the periodic table are called the halogens; elements in group 6A are called the chalcogens. (a) What is the most common oxidation state of the chalcogens compared to the halogens?
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Textbook Question
Note from the following table that there is a significant increase
in atomic radius upon moving from Y to La, whereas
the radii of Zr to Hf are the same. Suggest an explanation for
this effect.
Atomic Radii (pm)
Sc 170 Ti 160
Y 190 Zr 175
La 207 Hf 175
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Textbook Question
(c) Will the lithium cobalt oxide cathode expand or contract as lithium ions are inserted?
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