(a) If the core electrons were totally effective at screening the valence electrons and the valence electrons provided no screening for each other, what would be the effective nuclear charge acting on the 3s and 3p valence electrons in P?
Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 84
In Table 7.8, the bonding atomic radius of neon is listed as 58 pm, whereas that for xenon is listed as 140 pm. A classmate of yours states that the value for Xe is more realistic than the one for Ne. Is she correct? If so, what is the basis for her statement?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Atomic Radius
The atomic radius is a measure of the size of an atom, typically defined as the distance from the nucleus to the outermost electron shell. It varies across the periodic table, generally increasing down a group due to the addition of electron shells and decreasing across a period due to increased nuclear charge, which pulls electrons closer to the nucleus.
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Noble Gases and Their Properties
Noble gases, such as neon and xenon, are characterized by their complete valence electron shells, making them largely unreactive. However, their atomic radii differ significantly due to their position in the periodic table, with xenon being larger than neon. This difference is important when discussing bonding atomic radii, as it reflects the effective size of the atoms in various contexts.
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Bonding Atomic Radius vs. Van der Waals Radius
The bonding atomic radius refers to the size of an atom when it forms a bond with another atom, while the Van der Waals radius describes the size of an atom when it is not bonded but is in close proximity to another atom. The discrepancy in the atomic radii of neon and xenon can be attributed to their different bonding behaviors and the types of interactions they typically engage in, which can influence the perceived 'realism' of their atomic sizes.
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Related Practice
Textbook Question
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Textbook Question
(b) Repeat these calculations using Slater’s rules.
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Textbook Question
(d) If you remove a single electron from a P atom, which orbital will it come from?
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Textbook Question
The As ¬ As bond length in elemental arsenic is 2.48 Å. The Cl ¬ Cl bond length in Cl2 is 1.99 Å. (a) Based on these data, what is the predicted As ¬ Cl bond length in arsenic trichlo- ride, AsCl3, in which each of the three Cl atoms is bonded to the As atom?
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Textbook Question
The As ¬ As bond length in elemental arsenic is 2.48 Å. The Cl ¬ Cl bond length in Cl2 is 1.99 Å. (b) What bond length is predicted for AsCl3, using the atomic radii in Figure 7.7?
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Textbook Question
The following observations are made about two hypothetical
elements A and B: The A¬A and B¬B bond lengths in the
elemental forms of A and B are 236 and 194 pm, respectively.
A and B react to form the binary compound AB2, which has
a linear structure (that is B-A-B = 180°). Based on these
statements, predict the separation between the two B nuclei
in a molecule of AB2.
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