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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 84

In Table 7.8, the bonding atomic radius of neon is listed as 58 pm, whereas that for xenon is listed as 140 pm. A classmate of yours states that the value for Xe is more realistic than the one for Ne. Is she correct? If so, what is the basis for her statement?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Atomic Radius

The atomic radius is a measure of the size of an atom, typically defined as the distance from the nucleus to the outermost electron shell. It varies across the periodic table, generally increasing down a group due to the addition of electron shells and decreasing across a period due to increased nuclear charge, which pulls electrons closer to the nucleus.
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Noble Gases and Their Properties

Noble gases, such as neon and xenon, are characterized by their complete valence electron shells, making them largely unreactive. However, their atomic radii differ significantly due to their position in the periodic table, with xenon being larger than neon. This difference is important when discussing bonding atomic radii, as it reflects the effective size of the atoms in various contexts.
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Bonding Atomic Radius vs. Van der Waals Radius

The bonding atomic radius refers to the size of an atom when it forms a bond with another atom, while the Van der Waals radius describes the size of an atom when it is not bonded but is in close proximity to another atom. The discrepancy in the atomic radii of neon and xenon can be attributed to their different bonding behaviors and the types of interactions they typically engage in, which can influence the perceived 'realism' of their atomic sizes.
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