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Ch.7 - Periodic Properties of the Elements

Chapter 7, Problem 89c

(c) Will the lithium cobalt oxide cathode expand or contract as lithium ions are inserted?

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everyone in this example we have the following statement which says that the lithium cobalt oxide in a discharging lithium ion battery is blank for every lithium ion inserted. So we should recall that for lithium cobalt oxide. We have the following ions which would be R. L. I. Plus one ion. And then we would recall that cobalt because it's a transition metal occurs in the D. Block and has multiple ions. Being our Ceo three plus. Sorry that should be c. 0. 3 plus caddy on. And our Ceo four plus cat ion. And so because we have cat ions with a positive charge, we would say that therefore the electrode replace our lithium cobalt oxide in is placed in the cathode, which we recall occurs with a positive charge. So we can say that overall as lithium ions are inserted in the cathode, smaller Cobalt four plus ions are reduced. Two larger Cobalt three plus ions which ultimately expands our lithium cobalt oxide. And so to complete this example based on what we've outlined below, we can agree that the proper answer choice would be choice a where we would fill in saying that the lithium cobalt oxide in a discharging lithium ion battery expands for every lithium ion inserted. So I hope that everything I explained was clear. If you have any questions, please leave them down below and I will see everyone in the next practice video
Related Practice
Textbook Question
The following observations are made about two hypothetical elements A and B: The A¬A and B¬B bond lengths in the elemental forms of A and B are 236 and 194 pm, respectively. A and B react to form the binary compound AB2, which has a linear structure (that is B-A-B = 180°). Based on these statements, predict the separation between the two B nuclei in a molecule of AB2.
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Textbook Question

Elements in group 7A in the periodic table are called the halogens; elements in group 6A are called the chalcogens. (a) What is the most common oxidation state of the chalcogens compared to the halogens?

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Textbook Question
Note from the following table that there is a significant increase in atomic radius upon moving from Y to La, whereas the radii of Zr to Hf are the same. Suggest an explanation for this effect. Atomic Radii (pm) Sc 170 Ti 160 Y 190 Zr 175 La 207 Hf 175
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Textbook Question

(d) Lithium is not nearly as abundant as sodium. If sodium ion batteries were developed that function in the same manner as lithium ion batteries, do you think 'sodium cobalt oxide' would still work as the electrode material? Explain.

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Textbook Question

The ionic substance strontium oxide, SrO, forms from the reaction of strontium metal with molecular oxygen. The arrangement of the ions in solid SrO is analogous to that in solid NaCl: (a) Write a balanced equation for the formation of SrO(s) from its elements.

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Textbook Question

The ionic substance strontium oxide, SrO, forms from the reaction of strontium metal with molecular oxygen. The arrangement of the ions in solid SrO is analogous to that in solid NaCl:

(b) Based on the ionic radii in Figure 7.8, predict the length of the side of the cube in the figure (the distance from the center of an atom at one corner to the center of an atom at a neighboring corner).

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