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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 89d

(d) Lithium is not nearly as abundant as sodium. If sodium ion batteries were developed that function in the same manner as lithium ion batteries, do you think 'sodium cobalt oxide' would still work as the electrode material? Explain.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electrode Materials in Batteries

Electrode materials are crucial in battery technology as they determine the battery's capacity, voltage, and overall efficiency. In lithium-ion batteries, materials like lithium cobalt oxide are used due to their ability to intercalate lithium ions effectively. For sodium-ion batteries, the electrode materials must also accommodate sodium ions, which are larger than lithium ions, potentially affecting the material's performance.
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Ionic Size and Mobility

The size and mobility of ions play a significant role in the performance of battery electrodes. Sodium ions (Na+) are larger than lithium ions (Li+), which can lead to slower diffusion rates and reduced conductivity in the electrode material. This difference necessitates the exploration of alternative materials that can efficiently accommodate sodium ions while maintaining good electrochemical properties.
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Material Compatibility

Material compatibility refers to how well a specific electrode material can function with a given ion type in a battery system. Sodium cobalt oxide, while effective for lithium-ion systems, may not perform optimally with sodium ions due to structural and electrochemical differences. Understanding these compatibilities is essential for developing efficient sodium-ion batteries that can rival lithium-ion technology.
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Related Practice
Textbook Question

Elements in group 7A in the periodic table are called the halogens; elements in group 6A are called the chalcogens. (a) What is the most common oxidation state of the chalcogens compared to the halogens?

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Textbook Question
Note from the following table that there is a significant increase in atomic radius upon moving from Y to La, whereas the radii of Zr to Hf are the same. Suggest an explanation for this effect. Atomic Radii (pm) Sc 170 Ti 160 Y 190 Zr 175 La 207 Hf 175
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Textbook Question

(c) Will the lithium cobalt oxide cathode expand or contract as lithium ions are inserted?

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Textbook Question

The ionic substance strontium oxide, SrO, forms from the reaction of strontium metal with molecular oxygen. The arrangement of the ions in solid SrO is analogous to that in solid NaCl: (a) Write a balanced equation for the formation of SrO(s) from its elements.

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Textbook Question

The ionic substance strontium oxide, SrO, forms from the reaction of strontium metal with molecular oxygen. The arrangement of the ions in solid SrO is analogous to that in solid NaCl:

(b) Based on the ionic radii in Figure 7.8, predict the length of the side of the cube in the figure (the distance from the center of an atom at one corner to the center of an atom at a neighboring corner).

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Textbook Question

The ionic substance strontium oxide, SrO, forms from the reaction of strontium metal with molecular oxygen. The arrangement of the ions in solid SrO is analogous to that in solid NaCl:

(c) The density of SrO is 5.10 g>cm3. Given your answer to part (b), how many formula units of SrO are contained in the cube shown here?

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