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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 109b

The first 25 years of the twentieth century were momentous for the rapid pace of change in scientists' understanding of the nature of matter. (b) In what ways is de Broglie's hypothesis, as it applies to electrons, consistent with J. J. Thomson's conclusion that the electron has mass? In what sense is it consistent with proposals preceding Thomson's work that the cathode rays are a wave phenomenon?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

de Broglie's Hypothesis

de Broglie's hypothesis posits that particles, such as electrons, exhibit wave-like properties, characterized by a wavelength inversely proportional to their momentum. This duality suggests that electrons can behave both as particles and waves, which is fundamental in quantum mechanics. This concept helps bridge the understanding of electron behavior in atomic structures and supports the idea of quantized energy levels.
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Mass of the Electron

J. J. Thomson's experiments led to the discovery of the electron and established that it possesses mass, albeit very small compared to other particles. This finding was crucial in understanding the structure of atoms, as it indicated that electrons could influence atomic behavior and stability. The acknowledgment of the electron's mass is essential for reconciling classical physics with emerging quantum theories.
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Wave-Particle Duality

Wave-particle duality is a fundamental principle of quantum mechanics that describes how particles, like electrons, can exhibit both wave-like and particle-like properties. This concept was pivotal in the early 20th century, as it challenged classical physics notions and led to the development of quantum theory. The idea that cathode rays could behave as waves aligns with this duality, providing a framework for understanding electron behavior in various contexts.
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Related Practice
Textbook Question

In the experiment shown schematically below, a beam of neutral atoms is passed through a magnetic field. Atoms that have unpaired electrons are deflected in different directions in the magnetic field depending on the value of the electron spin quantum number. In the experiment illustrated, we envision that a beam of hydrogen atoms splits into two beams. (c) What do you think would happen if the beam of hydrogen atoms were replaced with a beam of helium atoms? Why?

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Textbook Question

The discovery of hafnium, element number 72, provided a controversial episode in chemistry. G. Urbain, a French chemist, claimed in 1911 to have isolated an element number 72 from a sample of rare earth (elements 58–71) compounds. However, Niels Bohr believed that hafnium was more likely to be found along with zirconium than with the rare earths. D. Coster and G. von Hevesy, working in Bohr's laboratory in Copenhagen, showed in 1922 that element 72 was present in a sample of Norwegian zircon, an ore of zirconium. (The name hafnium comes from the Latin name for Copenhagen, Hafnia). (a) How would you use electron configuration arguments to justify Bohr's prediction?

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Textbook Question

The discovery of hafnium, element number 72, provided a controversial episode in chemistry. G. Urbain, a French chemist, claimed in 1911 to have isolated an element number 72 from a sample of rare earth (elements 58–71) compounds. However, Niels Bohr believed that hafnium was more likely to be found along with zirconium than with the rare earths. D. Coster and G. von Hevesy, working in Bohr's laboratory in Copenhagen, showed in 1922 that element 72 was present in a sample of Norwegian zircon, an ore of zirconium. (The name hafnium comes from the Latin name for Copenhagen, Hafnia). (d) Using their electron configurations, account for the fact that Zr and Hf form chlorides MCl4 and oxides MO2.

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Textbook Question

The two most common isotopes of uranium are 235U and 238U. (b) Using the periodic table in the frontinside cover, write the electron configuration for a U atom.

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Textbook Question

The two most common isotopes of uranium are 235U and 238U. (d) 238U undergoes radioactive decay to 234Th. How many protons, electrons, and neutrons are gained or lost by the 238U atom during this process? (e) Examine the electron configuration for Th in Figure 6.31. Are you surprised by what you find? Explain.

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Textbook Question
(d) Treating bismuth with fluorine gas forms BiF5. Use the electron configuration of Bi to explain the formation of a compound with this formulation.
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