The first 25 years of the twentieth century were momentous for the rapid pace of change in scientists' understanding of the nature of matter. (b) In what ways is de Broglie's hypothesis, as it applies to electrons, consistent with J. J. Thomson's conclusion that the electron has mass? In what sense is it consistent with proposals preceding Thomson's work that the cathode rays are a wave phenomenon?
Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 114
(d) Treating bismuth with fluorine gas forms BiF5. Use the electron configuration of Bi to explain the formation of a compound with this formulation.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Electron Configuration
Electron configuration describes the distribution of electrons in an atom's orbitals. For bismuth (Bi), the electron configuration is [Xe] 4f14 5d10 6s2 6p3, indicating it has five valence electrons. Understanding this configuration is crucial for predicting how bismuth will interact with other elements, such as fluorine, to form compounds.
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Ionic Bonding
Ionic bonding occurs when atoms transfer electrons to achieve stable electron configurations, typically between metals and nonmetals. In the case of bismuth and fluorine, bismuth can lose its three p electrons, while fluorine, a highly electronegative element, gains electrons to form BiF5. This transfer leads to the formation of positively charged bismuth ions and negatively charged fluoride ions.
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Oxidation States
The oxidation state of an element indicates the degree of oxidation or reduction it has undergone in a compound. In BiF5, bismuth has an oxidation state of +5, meaning it has lost five electrons. This high oxidation state is significant as it reflects bismuth's ability to form stable compounds with highly electronegative elements like fluorine, which stabilizes the overall structure of the compound.
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Related Practice
Textbook Question
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Textbook Question
The two most common isotopes of uranium are 235U and 238U. (b) Using the periodic table in the frontinside cover, write the electron configuration for a U atom.
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Textbook Question
The two most common isotopes of uranium are 235U and 238U. (d) 238U undergoes radioactive decay to 234Th. How many protons, electrons, and neutrons are gained or lost by the 238U atom during this process? (e) Examine the electron configuration for Th in Figure 6.31. Are you surprised by what you find? Explain.
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